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931578

Sigma-Aldrich

Ruthenium(III)-chlorid Hydrat

≥99.9% trace metals basis

Synonym(e):

Ruthenium trichloride, Trichlororuthenium hydrate

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About This Item

Lineare Formel:
RuCl3 · xH2O
CAS-Nummer:
Molekulargewicht:
207.43 (anhydrous basis)
MDL-Nummer:
UNSPSC-Code:
12352302
NACRES:
NA.21

Qualitätsniveau

Assay

≥99.9% trace metals basis

Form

powder

Verunreinigungen

≤1000.0 ppm (trace metals analysis)

Löslichkeit

acetone: soluble ((lit.))
ethanol: soluble
water: soluble

Dichte

3.11 g/cm3

SMILES String

O.Cl[Ru](Cl)Cl

InChI

1S/3ClH.H2O.Ru/h3*1H;1H2;/q;;;;+3/p-3

InChIKey

BIXNGBXQRRXPLM-UHFFFAOYSA-K

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Allgemeine Beschreibung

Ruthenium chloride hydrate is a dark brown or black solid often used as a powder. The hydrate is hygroscopic and is soluble in water, ethanol, acetone, and a wide range of polar organic solvents. The anhydrous form is insoluble.
Industrially, ruthenium trichloride hydrate is produced by dissolving ruthenium oxides in hydrochloric acid. The hydrated salt is obtained by recrystallization.

Anwendung

Ruthenium chloride is most used as a precursor for the synthesis of ruthenium complexes. Our RuCl3·H2O with 99.9% trace metals purity is well-suited for applications in materials science. One common application of ruthenium trichloride hydrate is in the synthesis of ruthenium nanoparticles, which are used as catalysts or composited with other materials and used as co-catalysts for both oxygen and hydrogen evolution reactions. Researchers have used our ruthenium chloride hydrate to produce high-quality, catalytically active ruthenium nanoparticles and ruthenium oxide nanoparticles.
Another common application of ruthenium chloride hydrate is as a precursor for single-atom catalysts. For example, scientists have used ruthenium chloride hydrate for the synthesis of ruthenium single-atom-doped ZrO2 particles to catalyze nitrogen fixation and for the synthesis of ruthenium single-atom-doped MXenes to catalyze hydrogen evolution. A third common application of ruthenium chloride hydrate is in the synthesis of metal alloys, like PtRuIr, or PtRuFe, which are investigated for electrocatalysis, usually the oxidation of simple organics like methanol or formic acid.
For use in all these applications, also consider our higher-purity ruthenium chloride hydrate, 463779, with trace metals purity greater than 99.98%, which offers the best reproducibility and purity.

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B

Lagerklassenschlüssel

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable


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Synthesis and Activities of Rutile IrO2 and RuO2 Nanoparticles for Oxygen Evolution in Acid and Alkaline Solutions
Lee, Y., Suntivich, J., et al.
The Journal of Physical Chemistry Letters, 3, 399?404-399?404 (2012)
Heteroatom-Mediated Interactions between Ruthenium Single Atoms and an MXene Support for Efficient Hydrogen Evolution
Ramalingam, V., et al.
Advanced Materials, 31, e1903841-e1903841 (2019)
High Performance PtRuIr Catalysts Supported on Carbon Nanotubes for the Anodic Oxidation of Methanol
Liao, S., Holmes, K.A., et al.
Journal of the American Chemical Society, 128, 3504-3505 (2006)
Thermally Reduced Ruthenium Nanoparticles as a Highly Active Heterogeneous Catalyst for Hydrogenation of Monoaromatics
Su, F., Lv, L., et al.
Journal of the American Chemical Society, 129, 14213?14223-14213?14223 (2007)
Tailoring the composition of ultrathin, ternary alloy PtRuFe nanowires for the methanol oxidation reaction and formic acid oxidation reaction
Scofield, M.E., et al.
Energy & Environmental Science, 8, 350-350 (2015)

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