374377

2-(Triphenylphosphoranyliden)propionaldehyd

98%

• Synonym(e): 1-Formylethylidenetriphenylphosphorane
• Lineare Formel: (C₆H₅)₃P=C(CH₃)CHO
• CAS-Nummer: 24720-64-7
• Molekulargewicht: 318.35
• MDL-Nummer: MFCD00075596
• UNSPSC-Code: 12352114
• PubChem Substanz-ID: 24863304
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 100
• Assay: 98%
• Form: powder
• Eignung der Reaktion: reaction type: C-C Bond Formation
• mp (Schmelzpunkt): 219-221 °C (lit.)
• Funktionelle Gruppe: aldehyde; phosphine
• SMILES String: CC(C=O)=P(c1ccccc1)(c2ccccc2)c3ccccc3
• InChI: 1S/C21H19OP/c1-18(17-22)23(19-11-5-2-6-12-19,20-13-7-3-8-14-20)21-15-9-4-10-16-21/h2-17H,1H3
• InChIKey: VHUQEFAWBCDBSC-UHFFFAOYSA-N

Beschreibung

Anwendung

Reactant for:

• Preparation of acitretin analogs with antitumor activity
• Stereoselective synthesis of essential building blocks of phorboxazole A via hetero Diels-Alder and stereoselective hetero-Michael addition/equilibration
• Preparation of C1-C14 fragment of sarcoglaucol-16-one via Z-selective ando-type Horner-Wadsworth-Emmons olefination
• Wittig reactions
• Synthesis of ring-expanded and epothilone-hybridized macrosphelide analogs as apoptosis-inducing agents
• Preparation of phosphonic acid-containing analogs of mycophenolic acid as inhibitors of IMPDH

Sicherheitshinweise

• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: Eyeshields, Gloves, type N95 (US)