230200

Lithiumborhydrid -Lösung

2.0 M in THF

• Synonym(e): Lithium boron hydride, Lithium hydroborate
• Lineare Formel: LiBH₄
• CAS-Nummer: 16949-15-8
• Molekulargewicht: 21.78
• MDL-Nummer: MFCD00011088
• UNSPSC-Code: 12352302
• PubChem Substanz-ID: 24853783
• NACRES: NA.22

Eigenschaften

• Form: liquid
• Qualitätsniveau: 200
• Eignung der Reaktion: reagent type: reductant
• Konzentration: 2.0 M in THF
• Dichte: 0.896 g/mL at 25 °C
• SMILES String: [Li+].[H][B-]([H])([H])[H]
• InChI: 1S/BH4.Li/h1H4;/q-1;+1
• InChIKey: UUKMSDRCXNLYOO-UHFFFAOYSA-N

Beschreibung

Anwendung

Lithium borohydride solution (2M in THF) has been used for the reduction of 5-benzylidene-2,4-thiazolidinediones and 5-benzylidene-4-oxo-2-thiazolidinethiones to form 5-benzyl-2,4-thiazolidinediones and 5-benzyl-4-oxo-2-thiazolidinethiones, respectively.

Reactant for:

• Preparation of gallium, indium, rhenium and zinc tris(mercaptoimidazolyl)hydroborato complexes
• Mechano-chemical metathesis reactions
• Noncatalytic hydrolysis for hydrogen generation
• Growth of large gold monolayer protected-clusters
• Anion substitution reactions
• Dehydrogenation reactions

Verpackung

The 25 mL Sure/Seal^™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

Rechtliche Hinweise

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Sicherheitshinweise

• Piktogramme: GHS02,GHS08,GHS05,GHS07
• Signalwort: Danger
• H-Sätze: H225,H260,H302,H314,H335,H336,H351
• P-Sätze: P210 - P231 + P232 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Gefahreneinstufungen: Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1
• Zielorgane: Central nervous system, Respiratory system
• Zusätzliche Gefahrenhinweise: EUH019
• Lagerklassenschlüssel: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 2
• Flammpunkt (°F): -0.4 °F - closed cup
• Flammpunkt (°C): -18 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter