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분석
≥95%
양식
powder or solid
mp
120.5 °C
저장 온도
2-8°C
SMILES string
N1=C(OC[C@H]1C(=O)OC(C)(C)C)C3(CC3)C2=N[C@@H](CO2)C(=O)OC(C)(C)C
InChI
1S/C19H28N2O6/c1-17(2,3)26-13(22)11-9-24-15(20-11)19(7-8-19)16-21-12(10-25-16)14(23)27-18(4,5)6/h11-12H,7-10H2,1-6H3/t11-,12-/m0/s1
InChI key
LKXTWWHADOFMCC-RYUDHWBXSA-N
애플리케이션
sBOX(tBu) is a serine-derived chiral bisoxazoline ligand. The additional coordinating functionality provided by the esters enables new reactivity compared to traditional BOX ligands. sBOX(iPr) has been shown to be an optimal ligand for the electrocatalytic cyanophosphorylation as well as hydrocyanation of vinylarenes.
Product can be used with our Synlectro electrochemistry platform (ESYNTH001)
Product can be used with our Synlectro electrochemistry platform (ESYNTH001)
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
가장 최신 버전 중 하나를 선택하세요:
Niankai Fu et al.
Journal of the American Chemical Society, 141(37), 14480-14485 (2019-09-10)
In contrast to the rapid growth of synthetic electrochemistry in recent years, enantioselective catalytic methods powered by electricity remain rare. In this work, we report the development of a highly enantioselective method for the electrochemical cyanophosphinoylation of vinylarenes. A new
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