405973

2,2′-Bis[(4S)-4-benzyl-2-oxazoline]

98%

• 동의어(들): (S,S)-4,4′-Dibenzyl-2,2′-bi(2-oxazoline), (S,S)-2,2′-Bis(4-benzyl-2-oxazoline)
• 실험식(Hill 표기법): C₂₀H₂₀N₂O₂
• CAS Number: 133463-88-4
• Molecular Weight: 320.39
• Beilstein: 4756827
• MDL number: MFCD00191793
• UNSPSC 코드: 12352005
• PubChem Substance ID: 24865344
• NACRES: NA.22

속성

• 분석: 98%
• 양식: solid
• 광학 활성: [α]20/D −40.6°, c = 1 in ethanol
• mp: 129-132 °C (lit.)
• 작용기: ether; phenyl
• SMILES string: C1OC(=N[C@H]1Cc2ccccc2)C3=N[C@H](CO3)Cc4ccccc4
• InChI: 1S/C20H20N2O2/c1-3-7-15(8-4-1)11-17-13-23-19(21-17)20-22-18(14-24-20)12-16-9-5-2-6-10-16/h1-10,17-18H,11-14H2/t17-,18-/m0/s1
• InChI key: OIEQQWQZUYZCRJ-ROUUACIJSA-N

설명

애플리케이션

2,2′-Bis[(4S)-4-benzyl-2-oxazoline] can be used as:

• A catalyst for the enantioselective hydrosilylation of ketones.[1]
• A Schiff base ligand in the preparation of rhodium(I) and palladium(II) coordination complexes.[2]
• A ligand in the formation of copper(I) halide complexes; applicable in the synthesis of coordination polymers.[3]

안전성 정보

• 픽토그램: GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H315,H319,H335
• 예방조치 성명서: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 표적 기관: Respiratory system
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: dust mask type N95 (US), Eyeshields, Gloves