708682

RuCl[(R,R)-TsDPEN](mesitylene)

90%

• 동의어(들): [N-[(1R,2R)-2-(Amino-κN)-1,2- diphenylethyl]-4-methylbenzenesulfonamidato-κN]chloro [(1,2,3,4,5,6-η)-1,3,5-trimethylbenzene]-ruthenium
• 실험식(Hill 표기법): C₃₀H₃₃ClN₂O₂RuS
• CAS Number: 174813-82-2
• Molecular Weight: 622.18
• MDL number: MFCD12545951
• UNSPSC 코드: 12352116
• PubChem Substance ID: 329762817
• NACRES: NA.22

속성

• Quality Level: 100
• 분석: 90%
• 양식: solid
• mp: 241-249 °C
• 작용기: amine; phenyl
• 저장 온도: 2-8°C
• SMILES string: Cc1cc(C)cc(C)c1.Cc2ccc(cc2)S(=O)(=O)N([Ru]Cl)[C@@H]([C@H](N)c3ccccc3)c4ccccc4
• InChI: 1S/C21H21N2O2S.C9H12.ClH.Ru/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-7-4-8(2)6-9(3)5-7;;/h2-15,20-21H,22H2,1H3;4-6H,1-3H3;1H;/q-1;;;+2/p-1/t20-,21-;;;/m1.../s1
• InChI key: XBNBOGZUDCYNOJ-AGEKDOICSA-M

설명

애플리케이션

Takasago Ligands and Complexes for Asymmetric Reactions

RuCl[(R,R)-TsDPEN](mesitylene) may be used as a catalyst to synthesize:

• (2R,3S)-4-Benzyl-2-(hydroxyphenylmethyl)morpholin-3-one from racemic N-benzyl-2-benzoyl-3-morpholinone via dynamic kinetic resolution-based asymmetric transfer hydrogenation (ATH).[1]
• Chiral nonracemic δ-phenylseleno alcohols from δ-phenylseleno ketones via catalytic ATH reaction.[2]

법적 정보

Sold in collaboration with Takasago for research purposes only. WO9720789

안전성 정보

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: Eyeshields, Gloves, type N95 (US)