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Merck
모든 사진(3)

문서

682373

Sigma-Aldrich

Hoveyda-Grubbs Catalyst® M721

Umicore

동의어(들):

Hoveyda-Grubbs Catalyst® M72 SI(o-Tol) (C571), Dichloro[1,3-bis(2-methylphenyl)-2-imidazolidinylidene](2-isopropoxyphenylmethylene)ruthenium(II), Stewart-Grubbs catalyst

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About This Item

실험식(Hill 표기법):
C27H30Cl2N2ORu
CAS Number:
Molecular Weight:
570.52
MDL number:
UNSPSC 코드:
12161600
PubChem Substance ID:
NACRES:
NA.22

반응 적합성

core: ruthenium
reagent type: catalyst
reaction type: Ring-Opening Polymerization

mp

199-208 °C

저장 온도

2-8°C

SMILES string

CC(C)Oc1ccccc1C=[Ru](Cl)(Cl)=C2N(CCN2c3ccccc3C)c4ccccc4C

InChI

1S/C17H18N2.C10H12O.2ClH.Ru/c1-14-7-3-5-9-16(14)18-11-12-19(13-18)17-10-6-4-8-15(17)2;1-8(2)11-10-7-5-4-6-9(10)3;;;/h3-10H,11-12H2,1-2H3;3-8H,1-2H3;2*1H;/q;;;;+2/p-2

InChI key

ZDJCARGGZRTYFH-UHFFFAOYSA-L

애플리케이션

Less sterically hindered analog of Hoveyda-Grubbs Catalyst® 2nd Generation. Excels at ring-closing metathesis reactions of sterically encumbered olefins. Also useful for the cross metathesis of olefins bearing large allylic substituents.

법적 정보

Product of Umicore

Product License
This product, its manufacturing or use, is the subject of one or more issued or pending U.S. Patents (and foreign equivalents) owned or controlled by Umicore PMC. The purchase of this product from Umicore PMC through Sigma-Aldrich, its affiliates or their authorized distributors conveys to the buyer a limited, one-time, non-exclusive, non-transferable, non-assignable license. Buyer′s use of this product may infringe patents owned or controlled by third parties. It is the sole responsibility of buyer to ensure that its use of the product does not infringe the patent rights of third parties or exceed the scope of the license granted herein.

For any further information on product please refer to your local Umicore PMC contact at http://www.pmc.umicore.com
Grubbs Catalyst is a registered trademark of Umicore AG & Co. KG

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable


시험 성적서(COA)

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문서 라이브러리 방문

David E White et al.
Journal of the American Chemical Society, 130(3), 810-811 (2008-01-01)
Described in this report is the first total synthesis of elatol, a halogenated sesquiterpene in the chamigrene natural product family. The key disconnections in our synthetic approach include an enantioselective decarboxylative allylation to form the all-carbon quaternary stereocenter and a
Schrodi, Y.; Pederson, R.L.
Aldrichimica Acta, 40, 45-45 (2007)
Ian C Stewart et al.
Organic letters, 9(8), 1589-1592 (2007-03-24)
[reaction: see text] A series of ruthenium-based metathesis catalysts with N-heterocyclic carbene (NHC) ligands have been prepared in which the N-aryl groups have been changed from mesityl to mono-ortho-substituted phenyl (e.g., tolyl). These new catalysts offer an exceptional increase in

관련 콘텐츠

Olefin metathesis involves an organic reaction that redistributes fragments of alkenes (olefins) by cleavage and transformation of carbon-carbon double bonds.

Research in the Grubbs group has centered on the development and application of a suite of highly active, selective, and bench stable ruthenium alkylidene complexes capable of catalyzing versatile olefin metatheses.

자사의 과학자팀은 생명 과학, 재료 과학, 화학 합성, 크로마토그래피, 분석 및 기타 많은 영역을 포함한 모든 과학 분야에 경험이 있습니다..

고객지원팀으로 연락바랍니다.