569755

Hoveyda-Grubbs Catalyst^® M720

Umicore, 97%

• 동의어(들): Hoveyda-Grubbs Catalyst^® 2nd Generation, Hoveyda-Grubbs Catalyst^® M72 (C627), (1,3-Bis-(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(o-isopropoxyphenylmethylene)ruthenium, Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene](2-isopropoxyphenylmethylene)ruthenium(II), Grubbs Catalyst^® C627
• 실험식(Hill 표기법): C₃₁H₃₈Cl₂N₂ORu
• CAS Number: 301224-40-8
• Molecular Weight: 626.62
• MDL number: MFCD03701614
• UNSPSC 코드: 12161600
• PubChem Substance ID: 24880520
• NACRES: NA.22

속성

• Quality Level: 100
• 분석: 97%
• 형태: solid
• 반응 적합성: core: ruthenium; reagent type: catalyst; reaction type: Ring-Opening Polymerization
• mp: 216-220 °C (lit.)
• 저장 온도: 2-8°C
• SMILES string: CC(C)Oc1ccccc1C=[Ru](Cl)(Cl)=C2N(CCN2c3c(C)cc(C)cc3C)c4c(C)cc(C)cc4C
• InChI: 1S/C21H26N2.C10H12O.2ClH.Ru/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;1-8(2)11-10-7-5-4-6-9(10)3;;;/h9-12H,7-8H2,1-6H3;3-8H,1-2H3;2*1H;/q;;;;+2/p-2
• InChI key: ZRPFJAPZDXQHSM-UHFFFAOYSA-L

설명

애플리케이션

It′s a phosphine free version of Grubbs 2^nd Generation Catalyst with comparable reactivity, but initiates more readily at lower temperatures. Efficient for metathesis of electron-deficient substrates including fluorinated olefins. Demonstrated in multiple large-scale pharmaceutical applications.
It can be used as a catalyst for olefin cross-metathesis with fluorinated olefins (CM), ring-closing metathesis (RCM), ring-opening metathesis (ROM), and a sequence of a metathesis reaction and subsequent dihydroxylation of the newly formed double bond.

Learn more about our metathesis catalysts

기타 정보

Grubbs Catalyst^® Technology for Olefin Metathesis by Aldrich

법적 정보

Product of Umicore

Product License
This product, its manufacturing or use, is the subject of one or more issued or pending U.S. Patents (and foreign equivalents) owned or controlled by Umicore PMC. The purchase of this product from Umicore PMC through Sigma-Aldrich, its affiliates or their authorized distributors conveys to the buyer a limited, one-time, non-exclusive, non-transferable, non-assignable license. Buyer′s use of this product may infringe patents owned or controlled by third parties. It is the sole responsibility of buyer to ensure that its use of the product does not infringe the patent rights of third parties or exceed the scope of the license granted herein.

For any further information on product please refer to your local Umicore PMC contact at http://www.pmc.umicore.com

Grubbs Catalyst is a registered trademark of Umicore AG & Co. KG

안전성 정보

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: Eyeshields, Gloves, type N95 (US)