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Merck
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주요 문서

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556017

Sigma-Aldrich

N-Boc-4-piperidinemethanol

97%

동의어(들):

N-tert-Butyloxycarbonyl-4-piperidinemethanol

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모든 사진(1)

About This Item

실험식(Hill 표기법):
C11H21NO3
CAS Number:
123855-51-6
Molecular Weight:
215.29
MDL number:
MFCD02094488
UNSPSC 코드:
12352100
PubChem Substance ID:
24879512
NACRES:
NA.22

분석

97%

양식

solid

mp

78-82 °C (lit.)

작용기

hydroxyl

SMILES string

CC(C)(C)OC(=O)N1CCC(CO)CC1

InChI

1S/C11H21NO3/c1-11(2,3)15-10(14)12-6-4-9(8-13)5-7-12/h9,13H,4-8H2,1-3H3

InChI key

CTEDVGRUGMPBHE-UHFFFAOYSA-N

일반 설명

N-Boc-4-piperidinemethanol contains a tert-butyloxycarbonyl (t-BOC)-protecting group.[1] It can be synthesized from 4-piperidinemethanol via reaction with di-tert-butyldicarbonate.[2]

애플리케이션

N-Boc-4-piperidinemethanol may be used to synthesize:
  • methyl 5-methoxy-4-(1-methylpiperidin-4-ylmethoxy)-2-nitrobenzoate[1]
  • N-Boc-4-piperidinecarboxaldehyde[2]
  • [1-(tert-butoxycarbonyl)piperidin-4-yl]methyl methanesulfonate[3]
Involved in the synthesis of bradycardic agents.[4]

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

Eyeshields, Gloves, type N95 (US)

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시험 성적서(COA)

Lot/Batch Number
MKBQ8811V
MKBF5594V
MKBF5594
MKBB4389
MKAA3941

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Sigma-Aldrich

225541

Diisopropyl azodicarboxylate

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Sigma-Aldrich

T84409

Triphenylphosphine

Fluorine-18 labeling of 6, 7-disubstituted anilinoquinazoline derivatives for positron emission tomography (PET) imaging of tyrosine kinase receptors: synthesis of 18F-Iressa and related molecular probes.
Seimbille Y, et al.
Journal of Labelled Compounds & Radiopharmaceuticals, 48(11), 829-843 (2005)
Synthesis and nanostructures of 5, 10, 15, 20-tetrakis (4-piperidyl) porphyrin.
JacobsenJL, et al.
Tetrahedron, 69(48), 10507-10515 (2013)
Hideki Kubota et al.
Bioorganic & medicinal chemistry letters, 14(12), 3049-3052 (2004-05-20)
A series of piperidinoalkanoyl-1,2,3,4-tetrahydroisoquinoline derivatives were synthesized, and their bradycardic activities were investigated in the isolated right atria of guinea pigs and in conscious rats. These efforts identified the achiral compound 2f, which exhibited potent and long-lasting bradycardic activity with
Daniele Zampieri et al.
European journal of medicinal chemistry, 44(1), 124-130 (2008-04-29)
We describe here the synthesis and the binding interaction with sigma(1) and sigma(2) receptors of a series of new benzo[d]oxazol-2(3H)-one derivatives variously substituted on the N-benzyl moiety. The results of binding studies confirm the notion that the benzoxazolone moiety confers

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