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Merck
모든 사진(2)

주요 문서

393193

Sigma-Aldrich

Hydrocinnamaldehyde

technical grade, 90%

동의어(들):

3-Phenylpropionaldehyde

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100 ML
₩87,290

₩87,290


예상 입고일2025년 4월 21일세부사항


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100 ML
₩87,290

About This Item

Linear Formula:
C6H5CH2CH2CHO
CAS Number:
Molecular Weight:
134.18
Beilstein:
1071910
EC Number:
MDL number:
UNSPSC 코드:
12352100
PubChem Substance ID:
NACRES:
NA.22

₩87,290


예상 입고일2025년 4월 21일세부사항


벌크 견적 요청

Grade

technical grade

Quality Level

분석

90%

양식

liquid

불순물

<5% 3-phenyl-1-propanol

refractive index

n20/D 1.523 (lit.)

bp

97-98 °C/12 mmHg (lit.)

density

1.019 g/mL at 25 °C (lit.)

작용기

aldehyde
phenyl

SMILES string

[H]C(=O)CCc1ccccc1

InChI

1S/C9H10O/c10-8-4-7-9-5-2-1-3-6-9/h1-3,5-6,8H,4,7H2

InChI key

YGCZTXZTJXYWCO-UHFFFAOYSA-N

유사한 제품을 찾으십니까? 방문 제품 비교 안내

일반 설명

Hydrocinnamaldehyde is C=C double bond hydrogenated cinnamaldehyde. It has been synthesized by the selective hydrogenation of C=C double bond of cinnamaldehyde by various methods.[1][2][3][4][5] Hydrocinnamaldehyde and nitromethane undergoes Henry reaction to form nitroaldols.[6] The C1 and C3 position labelled with 13C of hydrocinnamaldehyde was subjected to mass spectrometry and the fragmentation pattern was elucidated.[7]

애플리케이션

Hydrocinnamaldehyde may be used in the synthesis of the following:
  • 2-Chloro hydrocinnamaldehyde by α-chlorination.[8]
  • Mixture of homopropargyl alcohols by kinetic resolution-allenylboration reactions.[9]
  • Mixture of syn- and anti-β-hydroxyallylsilanes by hydroboration of allenylsilane.[10]
  • (2S)-2-Hydroxy-4-phenylbutanenitrile by catalytic asymmetric cyanosilylation.[11]
  • Cinnamaldehyde by dehydrogenation reaction using Pd(TFA)2/4,5-diazafluorenone catalyst.[12]

Storage Class Code

10 - Combustible liquids

WGK

WGK 2

Flash Point (°F)

203.0 °F - closed cup

Flash Point (°C)

95 °C - closed cup

개인 보호 장비

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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문서 라이브러리 방문

Andy S Tsai et al.
Organic letters, 15(7), 1568-1571 (2013-03-15)
A chiral phosphoric acid catalyzed kinetic resolution/allenylboration of racemic allenylboronates with aldehydes is described. Allenylboration of aldehydes with 2.8 equiv of allenylboronate (±)-1 in the presence of 10 mol % of catalyst (R)-2 provided anti-homopropargyl alcohols 3 in 83-95% yield
Ming Chen et al.
Organic letters, 13(8), 1992-1995 (2011-03-18)
The kinetic hydroboration of allenylsilane 5 with ((d)Ipc)(2)BH at -40 °C provides allylborane 9Z with ≥12:1 selectivity. When the hydroboration is performed at temperatures above -40 °C, 9Z isomerizes to the thermodynamically more stable allylborane 9E with >20:1 selectivity. Subsequent
Influence of Preparation Modes on Pt-Ni/CNTs Catalysts Used in the Selective Hydrogenation of Cinnamaldehyde to Hydrocinnamaldehyde.
Li Y, et al
Catalysis Letters, 126(3-4), 280-285 (2008)
Carbon nanofiber supported palladium catalyst for liquid-phase reactions: An active and selective catalyst for hydrogenation of cinnamaldehyde into hydrocinnamaldehyde.
Pham-Huu C, et al
J. Mol. Catal. A: Chem., 170(1), 155-163 (2001)
Elucidation of elctron-impact-induced fragmentations of hydrocinnamaldehyde by 13C labelling; evidence for an 'ortho attack'in the molecular ion.
Venema A and Nibbering NMM
Org. Mass Spectrom., 9(6), 628-630 (1974)

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