362174

(Bicyclo[2.2.1]hepta-2,5-diene)dichloropalladium(II)

98%

• 동의어(들): Dichloro (norbornadiene)palladium(II), NSC 176915, PdCl₂(nbd)
• 실험식(Hill 표기법): C₇H₈Cl₂Pd
• CAS Number: 12317-46-3
• Molecular Weight: 269.46
• EC Number: 235-583-2
• MDL number: MFCD00134222
• UNSPSC 코드: 12352300
• PubChem Substance ID: 24862295
• NACRES: NA.22

속성

• 분석: 98%
• 반응 적합성: core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Cross Couplings; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst
• mp: 260 °C (dec.) (lit.)
• SMILES string: Cl[Pd]Cl.[CH]1[CH]C2[CH][CH]C1C2
• InChI: 1S/C7H8.2ClH.Pd/c1-2-7-4-3-6(1)5-7;;;/h1-4,6-7H,5H2;2*1H;/q;;;+2/p-2
• InChI key: BNCRZJHZZCMDNP-UHFFFAOYSA-L

설명

애플리케이션

Catalyst for:

• Aerobic kinetic resolution of secondary alcohols
• Kinetic oxidative resolution of 1-phenyl ethanol
• Oxidative kinetic resolution-Claisen rearrangement sequence
• Aerobic oxidation of secondary alcohols

안전성 정보

• 픽토그램: GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H315,H319,H335
• 예방조치 성명서: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 표적 기관: Respiratory system
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: dust mask type N95 (US), Eyeshields, Gloves