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Merck
모든 사진(4)

주요 문서

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299685

Sigma-Aldrich

Palladium(II) trifluoroacetate

97%

동의어(들):

Pd(TFA)2, Trifluoroacetic acid palladium(II) salt

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크기 선택

1 G
₩322,060
5 G
₩844,176

₩322,060

예상 입고일2025년 1월 27일세부사항

벌크 견적 요청
모든 사진(4)

크기 선택

보기 변경
1 G
₩322,060
5 G
₩844,176

About This Item

Linear Formula:
(CF3COO)2Pd
CAS Number:
42196-31-6
Molecular Weight:
332.45
MDL number:
MFCD00013204
UNSPSC 코드:
12161600
PubChem Substance ID:
24858054
NACRES:
NA.22

₩322,060

예상 입고일2025년 1월 27일세부사항

벌크 견적 요청

Quality Level

200

분석

97%

양식

solid

반응 적합성

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: C-H Activation

mp

~220 °C

SMILES string

FC(F)(F)C(=O)O[Pd]OC(=O)C(F)(F)F

InChI

1S/2C2HF3O2.Pd/c2*3-2(4,5)1(6)7;/h2*(H,6,7);/q;;+2/p-2

InChI key

PBDBXAQKXCXZCJ-UHFFFAOYSA-L

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일반 설명

Palladium(II) trifluoroacetate is a catalyst used in Suzuki-Miyaura, Heck, and Stille cross-coupling reactions.[1]

애플리케이션

Application Guide for Palladium Catalyzed Cross-Coupling Reactions
Catalyst used for the mild decarboxylation of electron-rich aromatic acids[2] and the direct cross-coupling of unactivated arenes.[3]
Catalyzes the selective allylic oxidation of geranylacetone and other olefins to their allyl acetates, which can then be converted to keto alcohols.[4]

픽토그램

Exclamation mark
GHS07

신호어

Warning

유해 및 위험 성명서

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

표적 기관

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

dust mask type N95 (US), Eyeshields, Gloves

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시험 성적서(COA)

Lot/Batch Number
MKCT6736
MKCS4523
MKCQ5496
MKCQ9029
MKCR5375

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문서 라이브러리 방문

Mu-Wang Chen et al.
Organic letters, 12(21), 5075-5077 (2010-10-06)
An enantioselective hydrogenation of simple fluorinated imines has been developed using Pd(OCOCF(3))(2)/(R)-Cl-MeO-BIPHEP as a catalyst, and up to 94% ee was achieved. This method provides an efficient route to enantioenriched fluorinated amines.
Keisuke Kato et al.
Angewandte Chemie (International ed. in English), 48(18), 3326-3328 (2009-02-05)
Boxing clever: Direct conversion of a terminal alkyne group into a beta-methoxyacrylate is realized with the aid of the bis(oxazoline) ligand (box). Acetyl and ketal protecting groups, free hydroxy groups, and acid-sensitive glycosidic bonds are not affected under the reaction
Palladium(II)-Catalyzed Direct ortho-C-H Acylation of Anilides by Oxidative Cross-Coupling with Aldehydes using tert-Butyl Hydroperoxide as Oxidant
Chan C, et al.
Advanced Synthesis & Catalysis, 353, 2999-3006 (2011)
Tetrahedron Letters, 25, 4187-4187 (1984)
Joshua S Dickstein et al.
Organic letters, 9(13), 2441-2444 (2007-06-05)
A palladium-catalyzed aromatic decarboxylation reaction has been developed. With electron-rich aromatic acids, the reaction proceeds efficiently under fairly mild conditions in good yields. The method was useful with complex functionalized substrates containing hindered carboxylic acids.
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