26235

2-(3-Chloropropyl)-1,3-dioxolane

≥97.0% (GC)

• 동의어(들): 4-Chlorobutyraldehyde ethylene acetal
• 실험식(Hill 표기법): C₆H₁₁ClO₂
• CAS Number: 16686-11-6
• Molecular Weight: 150.60
• Beilstein: 1236588
• MDL number: MFCD00043135
• UNSPSC 코드: 12352100
• PubChem Substance ID: 57648166
• NACRES: NA.22

속성

• Quality Level: 100
• 분석: ≥97.0% (GC)
• 양식: liquid
• refractive index: n20/D 1.453
• bp: 93-94 °C/12 mmHg (lit.)
• density: 1.142 g/mL at 20 °C (lit.)
• 작용기: chloro; ether
• SMILES string: ClCCCC1OCCO1
• InChI: 1S/C6H11ClO2/c7-3-1-2-6-8-4-5-9-6/h6H,1-5H2
• InChI key: ZBPUNVFDQXYNDY-UHFFFAOYSA-N

설명

애플리케이션

2-(3-Chloropropyl)-1,3-dioxolane (2-(3′-chloropropyl)-1,3-dioxolane) is a masked γ-chlorobutyraldehyde and was used for the introduction of 3-(1,3-dioxolan-2-yl)propyl moiety[1][2][3]. It was also used in the synthesis of:

• (±)-histrionicotoxin and (±)-histrionicotoxin 235A using a two-directional strategy[4]
• 4-iodobutyraldehyde, 5-iodovaleraldehyde and 5-iodo-2-petanone[5]
• corresponding phosphonate[6]

기타 정보

Masked γ-chlorobutyraldehyde, useful for the introduction of the 3-(1,3-dioxolan-2-yl)propyl moiety[1][2][3]; Preparation and use of the corresponding phosphonate[6]

안전성 정보

• Storage Class Code: 10 - Combustible liquids
• WGK: WGK 3
• Flash Point (°F): 174.2 °F - closed cup
• Flash Point (°C): 79 °C - closed cup
• 개인 보호 장비: Eyeshields, Gloves, type ABEK (EN14387) respirator filter