추천 제품
vapor pressure
6.8 psi ( 20 °C)
분석
99%
형태
liquid
refractive index
n20/D 1.385 (lit.)
bp
40 °C (lit.)
mp
−106-−105 °C (lit.)
density
0.691 g/mL at 25 °C (lit.)
SMILES string
CCCC#C
InChI
1S/C5H8/c1-3-5-4-2/h1H,4-5H2,2H3
InChI key
IBXNCJKFFQIKKY-UHFFFAOYSA-N
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일반 설명
Selective and non-selective hydrogenation of 1-pentyne catalyzed by silica-supported palladium has been studied by in situ X-ray absorption spectroscopy.
애플리케이션
1-Pentyne has been used in preparation of:
- lithium acetylides, required for asymmetric synthesis of α,α-dibranched propargyl sulfinamides
- 7-hydroxy-10-methoxy-3H-naphtho[2.1-b]pyrans
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Flam. Liq. 2
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point (°F)
-4.0 °F - closed cup
Flash Point (°C)
-20 °C - closed cup
개인 보호 장비
Eyeshields, Faceshields, Gloves
시험 성적서(COA)
제품의 로트/배치 번호를 입력하여 시험 성적서(COA)을 검색하십시오. 로트 및 배치 번호는 제품 라벨에 있는 ‘로트’ 또는 ‘배치’라는 용어 뒤에서 찾을 수 있습니다.
이미 열람한 고객
Journal of the American Chemical Society, 128(34), 11044-11053 (2006-08-24)
The carbene complex 5-(2,2-dimethyl-2H-chromene)methoxylmethylene chromium pentacarbonyl will undergo a benzannulation reaction with phenylacetylene, 1-pentyne, 3-hexyne, and trimethylsilylacetylene to give 7-hydroxy-10-methoxy-3H-naphtho[2.1-b]pyrans as the primary product. These compounds are difficult to obtain pure due to their sensitivity to air. If the benzannulation
The Journal of organic chemistry, 71(18), 7110-7112 (2006-08-26)
Addition of lithium acetylides prepared from 1-pentyne, phenylacetylene, and trimethylsilylacetylene to diverse N-tert-butanesulfinyl ketimines affords a range of alpha,alpha-dibranched propargyl sulfinamides in generally good yields (up to 87%) and with high diastereoselectivities (up to >99:1). Acidic cleavage of the tert-butanesulfinyl
Physical chemistry chemical physics : PCCP, 14(16), 5761-5768 (2012-03-17)
The catalytically active phase of silica-supported palladium catalysts in the selective and non-selective hydrogenation of 1-pentyne was determined using in situ X-ray absorption spectroscopy at the Pd K and L(3) edges. Upon exposure to alkyne, a palladium carbide-like phase rapidly
International journal of molecular sciences, 20(13) (2019-07-03)
Hydrogen atom abstraction from propargyl C-H sites of alkynes plays a critical role in determining the reactivity of alkyne molecules and understanding the formation of soot precursors. This work reports a systematic theoretical study on the reaction mechanisms and rate
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