935638

トリス(トリメチルシリル)ホスフェート

≥99.0%, anhydrous, battery grade

• 別名: りん酸トリス(トリメチルシリルエステル)
• 化学式: [(CH₃)₃SiO]₃P(O)
• CAS番号: 10497-05-9
• 分子量: 314.54
• Beilstein: 1794624
• MDL番号: MFCD00008267
• UNSPSCコード: 12352005

特性

• グレード: battery grade
• 品質水準: 100
• 詳細: Application: Battery manufacturing
• アッセイ: ≥99.0%
• フォーム: (colorless liquid)
• 環境により配慮した代替製品の特徴: Design for Energy Efficiency; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• 不純物: ppm H2O≤500; ≤500 ppm H₂O
• 屈折率: n20/D 1.409 (lit.)
• bp: 228-229 °C/720 mmHg (lit.); 228-229 °C
• mp: 3-4 °C (lit.); 3-4 °C
• 密度: 0.945 g/mL at 25 °C (lit.)
• アプリケーション: battery manufacturing
• 環境により配慮した代替製品カテゴリ: Enabling
• SMILES記法: C[Si](C)(C)OP(=O)(O[Si](C)(C)C)O[Si](C)(C)C
• InChI: 1S/C9H27O4PSi3/c1-15(2,3)11-14(10,12-16(4,5)6)13-17(7,8)9/h1-9H3
• InChI Key: QJMMCGKXBZVAEI-UHFFFAOYSA-N

詳細

詳細

Tris(trimethylsilyl) borate (TMSB) is an electron-deficient organoborate compound. It is a colorless liquid that that is miscible with many organic solvents, including the linear and cyclic carbonates used in battery applications. Our battery grade TMSB is differentiated by its high purity and low trace water content to ensure consistent and reliable performance in batteries.

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Click here for more information.

アプリケーション

Tris(trimethylsilyl) borate has a wide range of applications in various industries, including battery manufacturing, where it is used as an electrolyte additive, particularly in high-voltage lithium-ion batteries. TMSB is a cathode-film-forming additive that forms a thin protective coating called a solid-electrolyte interface (SEI) on the surface of the cathode. Adding TMSB to the electrolyte formulation, even at low concentrations of 0.5 wt.%, noticeably improves capacity retention for NMC, LMO, and LMNO cathodes.[1][2][3] TMSB also is shown to reduce the flammability of the electrolyte and improve the thermal stability of LiPF₆-based electrolytes at elevated temperatures.[3]TMSB also has catalytic properties, which make it useful in organic synthesis reactions and as a reagent in the manufacturing of pharmaceuticals and other chemicals.

安全性情報

• ピクトグラム: GHS02,GHS07
• シグナルワード: Danger
• 危険有害性情報: H225,H315,H319,H335
• 注意書き: P210 - P233 - P240 - P241 - P303 + P361 + P353 - P305 + P351 + P338
• 危険有害性の分類: Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
• ターゲットの組織: Respiratory system
• 保管分類コード: 3 - Flammable liquids
• WGK: WGK 2
• 引火点(°F): 55.4 °F - closed cup
• 引火点(℃): 13 °C - closed cup