774642

(ジエチルアミノ)硫黄トリフルオリド 溶液

1.0 M in dichloromethane

• 別名: DAST solution in dichloromethane
• 実験式（ヒル表記法）: C₄H₁₀F₃NS
• CAS番号: 38078-09-0
• 分子量: 161.19
• MDL番号: MFCD00000363
• UNSPSCコード: 12352101
• PubChem Substance ID: 329767703
• NACRES: NA.22

特性

• 形状: liquid
• 濃度: 1.0 M in dichloromethane
• 密度: 1.303 g/mL at 25 °C
• 保管温度: 2-8°C
• SMILES記法: CCN(CC)S(F)(F)F
• InChI: 1S/C4H10F3NS/c1-3-8(4-2)9(5,6)7/h3-4H2,1-2H3
• InChI Key: CSJLBAMHHLJAAS-UHFFFAOYSA-N

詳細

アプリケーション

• Fluorinating agent: reaction with alcohols and carbonyl compounds, Review
• Review on nucleophilic fluorination.
• Catalyst for Friedel-Crafts allylation using tertiary cyclopropyl silyl ethers and the rearrangement of homoallylic alcohols to unsaturated aldehydes.
• Early introduction of a fluoromethyl group stabilizes the epoxide during further manipulations in the synthesis of 26-fluoro-epothilone.
• Fluorinating agent for a variety of compounds, including thioethers, alkenols, and cyanohydrins.
• Reagent for gem difluorination of ketopipecolinic acids.

安全性情報

• ピクトグラム: GHS02,GHS08,GHS05,GHS07
• シグナルワード: Danger
• 危険有害性情報: H226,H314,H336,H351
• 注意書き: P202 - P210 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• 危険有害性の分類: Carc. 2 - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1A - STOT SE 3
• ターゲットの組織: Central nervous system
• 補足的ハザード: EUH014
• 保管分類コード: 3 - Flammable liquids
• WGK: WGK 3
• 引火点(°F): 75.2 °F
• 引火点(℃): 24 °C