551198

1-(4-Methylphenyl)-3-buten-1-ol

97%

• 別名: 1-p-Tolyl-but-3-en-1-ol
• 化学式: CH₃C₆H₄CH(OH)CH₂CH=CH₂
• CAS番号: 24165-63-7
• 分子量: 162.23
• MDL番号: MFCD03427119
• UNSPSCコード: 12352100
• PubChem Substance ID: 24879206
• NACRES: NA.22

特性

• アッセイ: 97%
• 屈折率: n20/D 1.5270 (lit.)
• bp: 253 °C (lit.)
• 密度: 0.983 g/mL at 25 °C (lit.)
• SMILES記法: Cc1ccc(cc1)C(O)CC=C
• InChI: 1S/C11H14O/c1-3-4-11(12)10-7-5-9(2)6-8-10/h3,5-8,11-12H,1,4H2,2H3
• InChI Key: RCKGDEZXTBRGHR-UHFFFAOYSA-N

詳細

詳細

1-(4-Methylphenyl)-3-buten-1-ol (1-p-tolyl-but-3-en-1-ol) is a homoallylic alcohol derivative. It can be prepared by the allylation of 4-methylbenzaldehyde using potassium allyltrifluoroborate in the presence of 18-crown-6.[1] It can undergo Prins cyclization with in the presence of cellulose-sulfonic acid to form the corresponding tetrahydropyran-4-ol.[2]

安全性情報

• ピクトグラム: GHS07
• シグナルワード: Warning
• 危険有害性情報: H315,H319,H335
• 注意書き: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• 危険有害性の分類: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• ターゲットの組織: Respiratory system
• 保管分類コード: 10 - Combustible liquids
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable
• 個人用保護具 (PPE): Eyeshields, Gloves, type ABEK (EN14387) respirator filter