361887

(1S,2S)-(+)-Thiomicamine

99%

• 別名: (1S,2S)-(+)-2-Amino-1-[4-(methylthio)phenyl]-1,3-propanediol
• 化学式: 4-(CH₃S)C₆H₄CH(OH)CH(NH₂)CH₂OH
• CAS番号: 16854-32-3
• 分子量: 213.30
• EC Number: 240-878-4
• MDL番号: MFCD00134212
• UNSPSCコード: 12352112
• PubChem Substance ID: 24862274
• NACRES: NA.22

特性

• アッセイ: 99%
• 光学活性: [α]25/D +25°, c = 1 in ethanol
• mp: 151-154 °C (lit.)
• SMILES記法: CSc1ccc(cc1)[C@H](O)[C@@H](N)CO
• InChI: 1S/C10H15NO2S/c1-14-8-4-2-7(3-5-8)10(13)9(11)6-12/h2-5,9-10,12-13H,6,11H2,1H3/t9-,10-/m0/s1
• InChI Key: IULJJGJXIGQINK-UWVGGRQHSA-N

詳細

アプリケーション

(1S,2S)-(+)-Thiomicamine can be used:

• As a starting material in the synthesis of 3,4-dihydroisoquinolinium salts, which are employed as promoters in asymmetric epoxidation and oxidation reactions.
• As a starting material in the synthesis of an α-amino acid named (3R,4R)-4-phenyl-1,2,3,4-tetrahydroisoquinoline-3-carboxylic acid, which is used to prepare modified peptides of biological importance.
• As a chiral base in the resolution of an angiotensin II type 2 receptor [AT₂R] antagonist named EMA401.

安全性情報

• ピクトグラム: GHS07
• シグナルワード: Warning
• 危険有害性情報: H315,H319,H335
• 注意書き: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• 危険有害性の分類: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• ターゲットの組織: Respiratory system
• 保管分類コード: 11 - Combustible Solids
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable
• 個人用保護具 (PPE): dust mask type N95 (US), Eyeshields, Gloves