328227

(1S)-(−)-Camphanic acid

98%

• 別名: (−)-Camphanic acid, (1S)-3-Oxo-4,7,7-trimethyl-2-oxabicyclo[2.2.1]heptane-1-carboxylic acid
• 実験式（ヒル表記法）: C₁₀H₁₄O₄
• CAS番号: 13429-83-9
• 分子量: 198.22
• Beilstein: 84570
• EC Number: 236-552-6
• MDL番号: MFCD00044948
• UNSPSCコード: 12352005
• PubChem Substance ID: 24859723
• NACRES: NA.22

特性

• アッセイ: 98%
• 光学活性: [α]20/D −18°, c = 1 in dioxane
• 光学純度: ee: 98% (GLC)
• mp: 201-204 °C (lit.)
• SMILES記法: CC1(C)[C@@]2(C)CC[C@@]1(OC2=O)C(O)=O
• InChI: 1S/C10H14O4/c1-8(2)9(3)4-5-10(8,6(11)12)14-7(9)13/h4-5H2,1-3H3,(H,11,12)/t9-,10+/m0/s1
• InChI Key: KPWKPGFLZGMMFX-VHSXEESVSA-N

詳細

詳細

(1S)-(-)-Camphanic acid is commonly used as a chiral auxiliary for the separation of racemates.

アプリケーション

(1S)-(-)-Camphanic acid may be used in the preparation of (-)-(1S,4R)-camphanoyl chloride by reacting with thionyl chloride.

安全性情報

• 保管分類コード: 13 - Non Combustible Solids
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable
• 個人用保護具 (PPE): Eyeshields, Gloves, type N95 (US)