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Sigma-Aldrich

2-Chloroacetophenone

purum, ≥98.0% (GC)

Sinonimo/i:

ω-Chloroacetophenone, Phenacyl chloride

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About This Item

Formula condensata:
C6H5COCH2Cl
Numero CAS:
532-27-4
Peso molecolare:
154.59
Beilstein:
507950
Numero CE:
208-531-1
Numero MDL:
MFCD00000933
Codice UNSPSC:
12352100
ID PubChem:
329767699
NACRES:
NA.22

Grado

purum

Livello qualitativo

200

Saggio

≥98.0% (GC)

Forma fisica

crystals

P. eboll.

244-245 °C (lit.)

Punto di fusione

53-56 °C
54-56 °C (lit.)

Densità

1.324 g/mL at 25 °C (lit.)

Stringa SMILE

ClCC(=O)c1ccccc1

InChI

1S/C8H7ClO/c9-6-8(10)7-4-2-1-3-5-7/h1-5H,6H2
IMACFCSSMIZSPP-UHFFFAOYSA-N

Informazioni sul gene

human ... PTPN6(5777)

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Categorie correlate

Descrizione generale

2-Chloroacetophenone is an organic building block used in the synthesis of heterocyclic compounds. It has low solubility in water but can be soluble in alcohols, ethers and other organic solvents.

Applicazioni

2-Chloroacetophenone can be used in the synthesis of phenyl acetic acid by Photo-Favorskii rearrangement. It is also used in the preparation of 1-(2-chlorophenyl)ethanol via asymmetric hydrogenation reaction.

Avvertenze

Danger

Classi di pericolo

Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Eye Dam. 1 - Resp. Sens. 1 - Skin Irrit. 2 - STOT SE 3

Organi bersaglio

Respiratory system

Codice della classe di stoccaggio

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

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Certificati d'analisi (COA)

Lot/Batch Number
0000375888
0000372760
0000375888
0000372760
0000213683

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Preparation of microgel-supported chiral catalysts and their application in the asymmetric hydrogenation of aromatic ketones
Deng J, et al.
Reactive and Functional Polymers, 72, 378-382 (2012)
Experimental study of the adsorption of 2-Chloroacetophenone at the air-environmental water interface
Hao, et al.
Frontiers in environmental science., 10, 2254-2254 (2022)
Lenilson C Rocha et al.
Biotechnology letters, 31(10), 1559-1563 (2009-06-06)
The asymmetric reduction of 2-chloro-1-phenylethanone (1) by seven strains of marine fungi was evaluated and afforded (S)-(-)-2-chloro-1-phenylethanol with, in the best case, an enantiomeric excess of 50% and an isolated yield of 60%. The ability of marine fungi to catalyse
Anil K Nigam et al.
Journal of hazardous materials, 184(1-3), 506-514 (2010-09-17)
Pyrolysis-GC/MS system with on-line micro-furnace was used to make rapid evaluation of ω-chloroacetophenone (CN) decomposition under inert thermal atmospheres. The volatile products evolved during pyrolysis were analyzed by thermal gravimetric analysis (TGA) and Py-GC/MS to obtain specific thermogram and pyrogram.
Expanding the [1,2]-aryl migration to the synthesis of substituted indoles.
Tao Pei et al.
Angewandte Chemie (International ed. in English), 47(22), 4231-4233 (2008-04-30)
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