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72240

Sigma-Aldrich

Aluminum-nickel alloy

purum, 50% Al basis, 50% Ni basis

Sinonimo/i:

Nickel-aluminum alloy, Raney®-Nickel alloy

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100 G
79,30 €
500 G
125,00 €

79,30 €


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Cambia visualizzazione
100 G
79,30 €
500 G
125,00 €

About This Item

Numero CAS:
Numero MDL:
Codice UNSPSC:
12161600
ID PubChem:
NACRES:
NA.22

79,30 €


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Livello qualitativo

Grado

purum

Stato

powder

Composizione

Al, 50%
Ni, 50%

Impiego in reazioni chimiche

core: nickel
reagent type: catalyst

Stringa SMILE

[Al].[Ni]

InChI

1S/Al.Ni
NPXOKRUENSOPAO-UHFFFAOYSA-N

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Applicazioni

Aluminum-nickel alloy can be used:
  • For the reduction of nitriles, nitro compounds and oximes to primary amines.[1]
  • For the conversion of carbonyl compounds to hydrocarbons.[2]
  • As a reducing agent to convert Ar-X derivatives to Ar-H compounds.[1]
  • For the synthesis of Raney nickel catalyst to be used as an alkylating agent.[3][4]
  • To synthesize non-pyrophoric Ni catalyst by alkali leaching.[5]
  • For the synthesis of alloyed skeletal Ni catalysts.[6]

Note legali

Raney is a registered trademark of W.R. Grace & Co.-Conn.

Sostituito da

N° Catalogo
Descrizione
Determinazione del prezzo

Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

Carc. 2 - Flam. Sol. 1 - Skin Sens. 1 - Water-react 2

Codice della classe di stoccaggio

4.3 - Hazardous materials which set free flammable gases upon contact with water

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Certificati d'analisi (COA)

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Highly selective hydrogenation of C?C double bond in unsaturated carbonyl compounds over NiC catalyst.
Mahata N, et al.
Chemical Engineering Journal, 188(4), 155-159 (2012)
Reinvestigating Raney nickel mediated selective alkylation of amines with alcohols via hydrogen autotransfer methodology.
Mehta A, et al.
Applied Catalysis A: General, 478(4), 241-251 (2014)
An environmentally benign and catalytically efficient non-pyrophoric Ni catalyst for aqueous-phase reforming of ethylene glycol.
Zhu LJ, et al.
Green Chemistry, 10(12), 1323-1330 (2008)
Reduction of carbonyl groups to the corresponding methylenes with Ni-Al alloy in water.
Ishimoto K, et al.
Chemical Communications (Cambridge, England), 89(4), 514-515 (2003)
Nickel-aluminum alloy as a reducing agent.
Keefer LK and Lunn G
Chemical Reviews, 89(3), 459-502 (1989)

Articoli

An article concerning self-propagating reactions induced by mechanical alloying, presented by Sigma-Aldrich.com.

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

Domande

1–2 di 2 domande  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 risposta
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Utile?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 risposta
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Utile?

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