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426318

Sigma-Aldrich

Tetrametilammonio idrossido

ACS reagent

Sinonimo/i:

N,N,N-trimethyl-methanaminium hydroxide, TMAH, TMAOH

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About This Item

Formula condensata:
(CH3)4N(OH)
Numero CAS:
75-59-2
Peso molecolare:
91.15
Beilstein:
3558708
Numero MDL:
MFCD00008280
Codice UNSPSC:
12352100
ID PubChem:
24866695
NACRES:
NA.21

Grado

ACS reagent

Livello qualitativo

200

Forma fisica

liquid

Concentrazione

1.0 M±0.02 M in H2O

Residuo alla calcinazione

≤5 ppm

Colore

APHA: ≤10

Indice di rifrazione

n20/D 1.3497

P. eboll.

100 °C

Densità

1.005 g/mL at 25 °C

Anioni in tracce

chloride (Cl-): ≤0.03%

Cationi in tracce

K: ≤2 ppm
Na: ≤2 ppm

Stringa SMILE

[OH-].C[N+](C)(C)C

InChI

1S/C4H12N.H2O/c1-5(2,3)4;/h1-4H3;1H2/q+1;/p-1
WGTYBPLFGIVFAS-UHFFFAOYSA-M

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Categorie correlate

Applicazioni

Tetramethylammonium hydroxide solution can be used as:
  • A reagent in the organocatalyzed photoinduced Birch reduction of arenes to 1,4-cyclohexadienes.
  • A catalyst to synthesize 1,2-dihydro-1-arylnaphtho-oxazine-3-one derivatives via one-pot three-component condensation reaction of 2-naphthol, aromatic aldehydes, and urea.
  • A peptizing agent for magnetite nanoparticles to promote repulsive stabilization forces.
  • A template in the hydrothermal synthesis of hierarchical zeolite T aggregates with different sizes.

Avvertenze

Danger

Indicazioni di pericolo

H301 + H311,H314,H371,H373,H412

Classi di pericolo

Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1B - STOT RE 2 Dermal - STOT SE 2

Organi bersaglio

Central nervous system, Liver,thymus

Codice della classe di stoccaggio

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificati d'analisi (COA)

Lot/Batch Number
MKCW5220
MKCV2454
MKCS1253
MKCQ2224
MKCN0479

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Tetraethylammonium hydroxide solution ~1.0 M (CH3CH2)4NOH in H2O, electrochemical grade

Supelco

86636

Tetraethylammonium hydroxide solution

Lina Barreto et al.
Eukaryotic cell, 10(9), 1241-1250 (2011-07-05)
Potassium homeostasis is crucial for living cells. In the yeast Saccharomyces cerevisiae, the uptake of potassium is driven by the electrochemical gradient generated by the Pma1 H(+)-ATPase, and this process represents a major consumer of the gradient. We considered that
Qin Chen et al.
Bioresource technology, 117, 186-192 (2012-05-23)
The aim of this study was to explore the synergies of laccase, a ligninolytic enzyme, with cellulose and hemicellulase amendments on ensiled corn stover. Molecular signals of lignin decomposition were observed by tetramethylammonium hydroxide thermochemolysis and gas chromatography-mass spectroscopy (TMAH-GC-MS)
Hui Chong et al.
Langmuir : the ACS journal of surfaces and colloids, 28(4), 2091-2098 (2011-11-08)
A new water-soluble conjugated polymer containing fluorene and boron-dipyrromethene repeat units in the backbones (PBF) that exhibits red emission was synthesized and characterized. Cationic PBF forms uniform nanoparticles with negatively charged disodium salt 3,3'-dithiodipropionic acid (SDPA) in aqueous solution through
Lulu Xie et al.
Science (New York, N.Y.), 342(6156), 373-377 (2013-10-19)
The conservation of sleep across all animal species suggests that sleep serves a vital function. We here report that sleep has a critical function in ensuring metabolic homeostasis. Using real-time assessments of tetramethylammonium diffusion and two-photon imaging in live mice
Mei Fang et al.
Nanotechnology, 23(14), 145601-145601 (2012-03-22)
Magnetite nanoparticles have been prepared by co-precipitation using a custom-designed jet mixer to achieve rapid mixing (RM) of reactants in a timescale of milliseconds. The quick and stable nucleation obtained allows control of the particle size and size distribution via
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