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Merck
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Documenti fondamentali

05689

Supelco

Diethyl ethoxymethylenemalonate

for LC-MS derivatization, LiChropur, ≥97.0% (GC)

Sinonimo/i:

DEEMM, Ethoxymethylenemalonic acid diethyl ester

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About This Item

Formula condensata:
C2H5OCH=C(COOC2H5)2
Numero CAS:
Peso molecolare:
216.23
Beilstein:
880058
Numero CE:
Numero MDL:
Codice UNSPSC:
41116105
ID PubChem:
NACRES:
NA.22

Livello qualitativo

Saggio

≥97.0% (GC)

Stato

liquid

Qualità

LiChropur

tecniche

LC/MS: suitable

Indice di rifrazione

n20/D 1.462 (lit.)

P. ebollizione

279-281 °C (lit.)

Densità

1.07 g/mL at 25 °C (lit.)

Stringa SMILE

CCO\C=C(\C(=O)OCC)C(=O)OCC

InChI

1S/C10H16O5/c1-4-13-7-8(9(11)14-5-2)10(12)15-6-3/h7H,4-6H2,1-3H3
LTMHNWPUDSTBKD-UHFFFAOYSA-N

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Risultati analitici

identification (LC-MS): identity conforms

Prodotti consigliati

Discover LiChropur reagents ideal for HPLC or LC-MS analysis

Note legali

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

Pittogrammi

Exclamation markEnvironment

Avvertenze

Warning

Indicazioni di pericolo

Classi di pericolo

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 2 - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1A

Codice della classe di stoccaggio

10 - Combustible liquids

Classe di pericolosità dell'acqua (WGK)

WGK 1

Punto d’infiammabilità (°F)

291.2 °F - closed cup

Punto d’infiammabilità (°C)

144 °C - closed cup


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Riin Rebane et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 904, 99-106 (2012-08-15)
Amino acid analysis with high performance liquid chromatography with electrospray ionization mass spectrometry (LC-ESI-MS) is an emerging method. For more sensitive analysis, derivatization is used and next to commercially available derivatization reagents such as dansyl chloride (DNS), 9-fluorenylmethyl chloroformate (FMOC-Cl)
Marta Perez et al.
Applied microbiology and biotechnology, 99(8), 3547-3558 (2014-12-23)
Enterococcus faecalis is a commensal bacterium of the human gut that requires the ability to pass through the stomach and therefore cope with low pH. E. faecalis has also been identified as one of the major tyramine producers in fermented
Cristina Megías et al.
Talanta, 131, 95-98 (2014-10-05)
A method for determination of the non-protein amino acid l-α-amino-γ-(guanidinooxy)-n-butyric acid (L-canavanine) and other free amino acids in Vicia disperma is presented. Seed extracts were derivatized by reaction with diethyl ethoxymethylenemalonate and analyzed by reverse-phase high-performance liquid chromatography. Calibration curves
Maarja-Liisa Oldekop et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 967, 147-155 (2014-08-12)
For liquid chromatographic analysis of amino acids involving derivatization and mass-spectrometric detection, it becomes more important to evaluate the presence of matrix effects in complex samples. This is somewhat complicated for amino acid analysis where analyte free sample matrix is
Patricia Alvarez-Sieiro et al.
Food chemistry, 168, 439-444 (2014-08-31)
For patients with celiac disease, gliadin detoxification via the use of gliadinases may provide an alternative to a gluten-free diet. A culture medium, in which gliadins were the sole source of nitrogen, was developed for screening for microorganisms with gliadinase

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