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P20602

Sigma-Aldrich

4-Phenyl-1-butene

99%

Sinonimo/i:

3-Butenylbenzene

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113,00 €
50 ML
385,00 €

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10 ML
113,00 €
50 ML
385,00 €

About This Item

Formula condensata:
C6H5CH2CH2CH=CH2
Numero CAS:
768-56-9
Peso molecolare:
132.20
Numero CE:
405-980-7
Numero MDL:
MFCD00026111
Codice UNSPSC:
12352100
ID PubChem:
24898267
NACRES:
NA.22

113,00 €

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Livello qualitativo

100

Saggio

99%

Indice di rifrazione

n20/D 1.507 (lit.)

P. ebollizione

175-177 °C (lit.)

Densità

0.88 g/mL at 25 °C (lit.)

Stringa SMILE

C=CCCc1ccccc1

InChI

1S/C10H12/c1-2-3-7-10-8-5-4-6-9-10/h2,4-6,8-9H,1,3,7H2
PBGVMIDTGGTBFS-UHFFFAOYSA-N

Categorie correlate

Applicazioni

4-Phenyl-1-butene can be used as a monomer precursor to synthesize poly(4-phenyl-1-butene) via heterogeneous catalytic-polymerization reaction. It is also utilized to make olefinic copolymers with different substrates, such as 11-bromo-1-undecene, ethylene, and vinylpyrrolidone, etc., for a variety of polymer applications.[1][2][3]
It can also be used as a reactant to synthesize:
  • (3-Chlorobutyl)benzene via cobalt catalyzed hydrochlorination reaction.[4]
  • Naphthalene by Cu-Pt alloy catalyzed dehydrocyclization reaction.[5]

Avvertenze

Warning

Indicazioni di pericolo

H226,H315,H411

Classi di pericolo

Aquatic Chronic 2 - Flam. Liq. 3 - Skin Irrit. 2

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 2

Punto d’infiammabilità (°F)

140.0 °F - closed cup

Punto d’infiammabilità (°C)

60 °C - closed cup

Dispositivi di protezione individuale

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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Certificati d'analisi (COA)

Lot/Batch Number
SHBM5203
SHBJ8194
STBD1157V
STBB4491V
39196CMV

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Sigma-Aldrich

282510

2-Methyl-1-phenyl-1-propene

Synthesis of (3-Chlorobutyl) benzene by the Cobalt-Catalyzed Hydrochlorination of 4-Phenyl-1-Butene
Gaspar Boris, et al.
Organic Syntheses, 87, 88-94 (2003)
Synthesis and properties of quaternized polyolefins with bulky poly (4-phenyl-1-butene) moieties as anion exchange membranes
Zhu Meng, et al.
Journal of Membrane Science , 541, 244-252 (2017)
Use of β-cyclodextrins to control the structure of water-soluble copolymers with hydrophobic parts
Nielsen AL, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 47(23), 6619-6629 (2009)
Copolymerization of ethylene with aromatic vinyl monomers using metallocenes
Kumar KR and Sivaram S
Polymer International, 50(4), 367-374 (2001)
Naphthalene formation on Cu3Pt (111): dehydrocyclization of 4-phenyl-1-butene
Mathauser AT and Teplyakov AV
Catalysis Letters, 73(2), 207-210 (2001)

Domande

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 risposta

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Utile?

  2. How can I determine the shelf life / expiration / retest date of this product?

    1 risposta

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Utile?

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