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P14831

Sigma-Aldrich

Phenothiazine

≥98%

Sinonimo/i:

Dibenzo-1,4-thiazine, Thiodiphenylamine, 10H-Phenothiazine

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About This Item

Formula empirica (notazione di Hill):
C12H9NS
Numero CAS:
92-84-2
Peso molecolare:
199.27
Beilstein:
143237
Numero CE:
202-196-5
Numero MDL:
MFCD00005015
Codice UNSPSC:
12352103
ID PubChem:
24898205
NACRES:
NA.23

Saggio

≥98%

P. eboll.

371 °C (lit.)

Punto di fusione

182-187 °C (lit.)

Stringa SMILE

N1c2ccccc2Sc3ccccc13

InChI

1S/C12H9NS/c1-3-7-11-9(5-1)13-10-6-2-4-8-12(10)14-11/h1-8,13H
WJFKNYWRSNBZNX-UHFFFAOYSA-N

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Categorie correlate

Descrizione generale

Phenothiazine is a versatile building block that can be easily functionalized as it possesses multiple modification sites. Its unique butterfly configuration and electron-rich character are beneficial for its potential use in optoelectronic applications. As it can undergo fast and reversible electron transfer reactions, it is widely used as photoactive material in organic light-emitting devices and solar cells.

Applicazioni

Phenothiazine can be used in the following applications:
  • It can be connected to carbazole by C-N linkage to increase the hole mobility and thermal stability in organic light-emitting devices.
  • Used in the fabrication of CMA-based (Carbene-Metal-Amide) white light-emitting OLED.
  • It is used as a starting material in the synthesis of dialdehyde monomer. A conjugated copolymer is prepared using this dialdehyde monomer, which is applicable as an emitting layer in PLED.
  • Used as a building block in the synthesis of conjugated dendrimers, for the development of light-emitting devices.

Avvertenze

Warning

Indicazioni di pericolo

H302,H317,H373,H410

Classi di pericolo

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Skin Sens. 1 - STOT RE 2 Oral

Organi bersaglio

Blood

Codice della classe di stoccaggio

13 - Non Combustible Solids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

Certificati d'analisi (COA)

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Indian J. Chem. B, 33, 397-397 (1994)
Alexander S Romanov et al.
Chemical science, 11(2), 435-446 (2020-03-20)
Conformationally flexible "Carbene-Metal-Amide" (CMA) complexes of copper and gold have been developed based on a combination of sterically hindered cyclic (alkyl)(amino)carbene (CAAC) and 6- and 7-ring heterocyclic amide ligands. These complexes show photoemissions across the visible spectrum with PL quantum
Mol. Cryst. Liq. Cryst. Sci. Technol., Sect. A, 237, 419-419 (1993)
Rajendra Kumar Konidena et al.
The Journal of organic chemistry, 80(11), 5812-5823 (2015-05-08)
A series of thienylphenothiazine decorated carbazoles were synthesized and characterized by optical, electrochemical, thermal, and theoretical investigations. Absorption spectra of the compounds are influenced by the substitution pattern and chromophore number density. Compounds containing 2,7-substitution exhibited red-shifted absorption, while the
Synthesis of p-type conjugated dendrimers bearing phenothiazine moiety at the periphery and their light-emitting device characterization
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