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D62209

Sigma-Aldrich

trans-1,2-Dichloroethylene

98%

Sinonimo/i:

trans-1,2-Dichloroethene, trans-Acetylene dichloride

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150,00 €

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5 G
50,00 €
25 G
99,30 €
100 G
150,00 €

About This Item

Formula condensata:
ClCH=CHCl
Numero CAS:
Peso molecolare:
96.94
Beilstein:
1420761
Numero CE:
Numero MDL:
Codice UNSPSC:
12352100
ID PubChem:
NACRES:
NA.22

50,00 €


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Tensione di vapore

5.16 psi ( 20 °C)

Saggio

98%

Stato

liquid

Limite di esplosione

12.8 %

Indice di rifrazione

n20/D 1.446 (lit.)

P. ebollizione

48 °C (lit.)

Punto di fusione

−50 °C (lit.)

Densità

1.257 g/mL at 25 °C (lit.)

Stringa SMILE

Cl\C=C\Cl

InChI

1S/C2H2Cl2/c3-1-2-4/h1-2H/b2-1+
KFUSEUYYWQURPO-OWOJBTEDSA-N

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Categorie correlate

Descrizione generale

trans-1,2-Dichloroethylene is an organic solvent used in freon cleaning agents. [1]

Applicazioni

trans-1,2-Dichloroethylene can be involved in the synthesis of:
  • (E)-Chloroenynes by reacting with 1-alkyne and piperidine in the presence of PdCl2(PPh3)2 catalyst in ethyl ether as a solvent.[2]
  • (E)-3-trimethylsilyl-1-chloro-1-propene by reacting with trimethylsilylmethylmagnesium chloride (TMSCH2MgCl) in the presence of Co(II) or Co(III) acetylacetonate.[3]
  • trans-1,2-Bis(tri-n-butylstannyl)ethylene which is an important reagent for the synthesis of myriad of natural products.[4]
  • trans-1-Chloroalkenes by reacting with Grignard reagents in the presence of tetrakis(triphenylphosphine)nickel as catalyst.[5]

Accessorio

N° Catalogo
Descrizione
Determinazione del prezzo

Pittogrammi

FlameExclamation mark

Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

Acute Tox. 4 Inhalation - Aquatic Chronic 3 - Flam. Liq. 2

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 2

Punto d’infiammabilità (°F)

42.8 °F - closed cup

Punto d’infiammabilità (°C)

6.0 °C - closed cup

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves


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Certificati d'analisi (COA)

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I clienti hanno visto anche

Slide 1 of 4

1 of 4

Cobalt-catalyzed mono-coupling of R3SiCH2MgCl with 1, 2-dihalogenoethylene: a general route to γ-substituted (E)-allylsilanes.
Kamachi T, et al.
Tetrahedron Letters, 45(24), 4677-4679 (2004)
Suzuki Coupling Reactions of (E)-and (Z)-Chloroenynes with Boronic Acids: Versatile Access to Functionalized 1, 3-Enynes
Tikad A, et al.
European Journal of Organic Chemistry, 2010(4), 725-731 (2010)
A convenient preparation of trans(or cis)-1-chloroalkenes from trans(or cis)-1, 2-dichloroethylene: A new synthesis of the sex pheromone of lobesia botrana.
Ratovelomanana V and Linstrumelle G
Tetrahedron Letters, 22(4), 315-318 (1981)
Preparation of trans-1, 2-bis(tributylstannyl) ethylene.
Corey EJ and Wollenberg RH
The Journal of Organic Chemistry, 40(25), 3788-3789 (1975)
Developmental toxicity of inhaled trans-1, 2-dichloroethylene in the rat
Hurtt, et al.
Fundamental and Applied Toxicology, 20, 225-230 (1993)

Domande

1–2 di 2 domande  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 risposta
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Utile?

  2. How can I determine the shelf life / expiration / retest date of this product?

    1 risposta
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Utile?

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