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934046

Sigma-Aldrich

Ethyl 1,1,2,2-tetrafluoroethyl ether

greener alternative

≥99%, anhydrous, battery grade

Sinonimo/i:

1,1,2,2-Tetrafluoroethyl ethyl ether, 1-Ethoxy-1,1,2,2-tetrafluoroethane, ETFE, HFE 374

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About This Item

Formula empirica (notazione di Hill):
C4H6F4O
Numero CAS:
Peso molecolare:
146.08
Numero MDL:
Codice UNSPSC:
12352100
ID PubChem:
NACRES:
NA.21

Grado

battery grade

Livello qualitativo

Saggio

≥99%

Forma fisica

liquid

Caratteristiche più verdi

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

Impurezze

≤100 ppm HF
≤200 ppm H2O

P. eboll.

58 °C

Punto di fusione

-86 °C (lit.)

Densità

1.21 g/mL

applicazioni

battery manufacturing

Categoria alternativa più verde

Descrizione generale

Ethyl 1,1,2,2-tetrafluoroethyl ether (ETFE) is a fluorinated linear ether that has several key properties that make it useful in batteries. First, ETFE is miscible with many polar organic solvents used in electrolyte formulations, which improves the ionic conductivity of the battery. Additionally, ETFE has a relatively low viscosity (486 mPa•s at 23 °C) and a low boiling point (58 °C), which make it a versatile diluent for low-temperature applications. Our battery grade ETFE is manufactured with high purity and low trace impurities of water and acid.
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Applicazioni

Ethyl 1,1,2,2-tetrafluoroethyl ether (ETFE) is a highly effective additive in lithium-ion batteries and sodium-ion batteries for improving battery performance, increasing safety, and reducing flammability. ETFE is a versatile co-solvent with high miscibility, which allows it to be blended with other solvents to achieve high ionic conductivities. It is also a good SEI-forming electrolyte additive, stabilizing the Na electrode surface and enhancing the stability of high-voltage batteries. ETFE is particularly useful as an electrolyte co-solvent in lithium-sulfur (Li-S) batteries. Studies have shown that ETFE-containing electrolytes improve the stability of the electrolyte/anode interface and enhance the cycling, rate, and self-discharging of the Li-S cell more than glyme-based cosolvents or unblended solvents. With its unique properties and proven effectiveness, battery-grade ETFE is an excellent choice for manufacturers looking to create high-performing, reliable, and safe lithium-ion and sodium-ion batteries.

Pittogrammi

Flame

Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

Flam. Liq. 2

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

5.0 °F

Punto d’infiammabilità (°C)

-15 °C


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Synthesis and electrochemical properties of partially fluorinated ether solvents for lithium sulfur battery electrolytes,
Yue , et al.
Journal of Power Sources, 401, 271-277 (2018)
Lithium/sulfur batteries with mixed liquid electrolytes based on ethyl 1,1,2,2-tetrafluoroethyl ether,
Hai, et al.
Electrochimica Acta, 161, 55-62 (2015)
Nasim Azimi et al.
ACS applied materials & interfaces, 7(17), 9169-9177 (2015-04-14)
A high performance Li-S battery with novel fluoroether-based electrolyte was reported. The fluorinated electrolyte prevents the polysulfide shuttling effect and improves the Coulombic efficiency and capacity retention of the Li-S battery. Reversible redox reaction of the sulfur electrode in the

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