923443

PhMPhos

• Sinonimo/i: 1-Diadamantylphosphino-1′-diphenylphosphinoferrocene
• Formula empirica (notazione di Hill): C₄₂H₄₈FeP₂
• Peso molecolare: 670.62
• Codice UNSPSC: 12352200
• NACRES: NA.21

Proprietà

• Stato: powder
• Livello qualitativo: 100
• Impiego in reazioni chimiche: reagent type: catalyst; reaction type: Cross Couplings; reagent type: ligand
• Caratteristiche più verdi: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• Gruppo funzionale: phosphine
• Categoria alternativa più verde: Aligned

Descrizione

Descrizione generale

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Applicazioni

PhMPhos is an unsymmetrical ferrocene-based phosphine ligand. The MPhos series of ligands are unsymmetrical diphosphino-ferrocenes bearing a bulky adamantyl group. Pd catalysts containing PhMPhos can be used for a variety of cross-coupling transformations, including Suzuki coupling, C-P coupling, and Csp²-Csp³ coupling. Demonstrated Csp²-Csp³ couplings include Murahashi-Feringa Coupling (Alkyl-Li), Kumada-Corriu coupling (Alkyl-MgX), Negishi coupling (Alkyl-ZnX) and Suzuki–Miyaura coupling (Alkyl-B(OR₂)).

Learn more about MPhos ligands and catalysts

Altre note

Tunable Unsymmetrical Ferrocene Ligands Bearing a Bulky Di-1-adamantylphosphino Motif for Many Kinds of Csp²–Csp³ Couplings

Informazioni sulla sicurezza

• Codice della classe di stoccaggio: 11 - Combustible Solids
• Classe di pericolosità dell'acqua (WGK): WGK 3
• Punto d’infiammabilità (°F): Not applicable
• Punto d’infiammabilità (°C): Not applicable