916803

1 M Biphenyl in THF

a precursor solution to prepare the prelithiation/presodiation reagent for disordered carbon, SiO, Sn, Sb, P, and S electrodes

• Formula empirica (notazione di Hill): C₁₂H₁₀
• Peso molecolare: 154.21
• Numero MDL: MFCD00003054
• Codice UNSPSC: 12352401
• NACRES: NA.23

Proprietà

• Livello qualitativo: 100
• Stato: liquid
• Concentrazione: 1 M
• Impurezze: ≤1000 ppm H₂O
• applicazioni: battery manufacturing
• Temperatura di conservazione: 2-8°C
• Stringa SMILE: c2(ccccc2)c1ccccc1
• InChI: ZUOUZKKEUPVFJK-UHFFFAOYSA-N

Descrizione

Applicazioni

This product is biphenyl (Bp) solution in anhydrous THF (1 mol/L) is a precursor reagent that could be easily handled to prepare prelithiation or presodiation reagent. By direct reaction of Li metal, it forms a strong reducing reagent of Li-Bp. The resulting Li-Bp/THF reagent has the redox potential of 0.41 V vs. Li/Li⁺, which is applicable to prelithiate most of the active materials for Li ion batteries, such as Sn, Sb, P, S, SiO and other metal oxide. On the other hand, a presodiation reagent can be prepared by reacting Bp/THF solution with Na metal. Na-Bp/THF reagent can be used to presodiate hard carbon, a promising anode material in Na ion batteries.[1][2]

Nota sulla preparazione

Suggested Directions for use:

• Step 1 Preparation of Prelithiation/presodiation reagent

Before use of Li metal, scrub the lithium surface to remove oxide and nitride layers.
To prepare 1 M Li-Bp/THF reagent, > 0.07 g of Li metal is added into every 10 ml of 1 M BP/THF solution
To prepare 1 M Na-Bp/THF reagent, > 0.23 g of Na metal is added into every 10 ml of 1 M BP/THF solution

• Step 2 Prelithiation/presodiation of electrodes

For a 1 cm diameter electrode with 1-3 mg acitve material per cm², soak (10-60 min, times will vary with material) the electrode in ∼0.5-1 mL of prelithiation/presodiation reagent. Discard the solution and then wash the electrode twice with THF. Longer prelithiation/presodiation time may cause electrode structure deformation, leading to a decreased discharge/charge capacity.

Informazioni sulla sicurezza

• Pittogrammi: GHS02,GHS08,GHS07,GHS09
• Avvertenze: Danger
• Indicazioni di pericolo: H225,H302,H315,H319,H335,H336,H351,H411
• Consigli di prudenza: P210 - P273 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338 - P308 + P313
• Classi di pericolo: Acute Tox. 4 Oral - Aquatic Chronic 2 - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
• Organi bersaglio: Central nervous system, Respiratory system
• Rischi supp: EUH018,EUH019
• Codice della classe di stoccaggio: 3 - Flammable liquids
• Classe di pericolosità dell'acqua (WGK): WGK 2
• Punto d’infiammabilità (°F): 1.4 °F
• Punto d’infiammabilità (°C): -17 °C