704954

XPhos Pd G1

• Sinonimo/i: (2-Dicyclohexylphosphino-2′,4′,6′-triisopropyl-1,1′-biphenyl)[2-(2-aminoethyl)phenyl)]palladium(II) chloride, (XPhos) palladium(II) phenethylamine chloride, Chloro(2-dicyclohexylphosphino-2′,4′,6′-triisopropyl-1,1′-biphenyl)[2-(2-aminoethyl)phenyl)]palladium(II), XPhos Palladacycle, XPhos precatalyst
• Formula empirica (notazione di Hill): C₄₁H₅₉ClNPPd
• Numero CAS: 1028206-56-5
• Peso molecolare: 738.76
• Numero MDL: MFCD13194128
• Codice UNSPSC: 12161600
• ID PubChem: 329762494
• NACRES: NA.22

Proprietà

• Forma fisica: solid
• Livello qualitativo: 100
• Caratteristiche: generation 1
• Impiego in reazioni chimiche: core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst; reaction type: Cross Couplings
• Punto di fusione: 205-210 °C
• Gruppo funzionale: phosphine
• Stringa SMILE: NCCc1ccccc1[Pd]Cl.CC(C)c2cc(C(C)C)c(c(c2)C(C)C)-c3ccccc3P(C4CCCCC4)C5CCCCC5
• InChI: 1S/C33H49P.C8H10N.ClH.Pd/c1-23(2)26-21-30(24(3)4)33(31(22-26)25(5)6)29-19-13-14-20-32(29)34(27-15-9-7-10-16-27)28-17-11-8-12-18-28;9-7-6-8-4-2-1-3-5-8;;/h13-14,19-25,27-28H,7-12,15-18H2,1-6H3;1-4H,6-7,9H2;1H;/q;;;+1/p-1; HTAJCNQBAFZEJO-UHFFFAOYSA-M

Descrizione

Descrizione generale

Material may contain up to 5% pentane

Applicazioni

Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Catalyst used for:

• Amination / cyclization reactions
• C-N bond-forming reactions via packed-bed microreactors
• Boration of aryl chlorides
• Arylation of oxazole
• Cross-coupling reactions

Note legali

Usage subject to US Patents 6307087 and 6395916.

Informazioni sulla sicurezza

• Pittogrammi: GHS07
• Avvertenze: Warning
• Indicazioni di pericolo: H315,H319,H335,H412
• Consigli di prudenza: P261 - P264 - P271 - P273 - P302 + P352 - P305 + P351 + P338
• Classi di pericolo: Aquatic Chronic 3 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Organi bersaglio: Respiratory system
• Codice della classe di stoccaggio: 11 - Combustible Solids
• Classe di pericolosità dell'acqua (WGK): WGK 3
• Dispositivi di protezione individuale: dust mask type N95 (US), Eyeshields, Gloves