489492
(1S-cis)-3-Bromo-3,5-cyclohexadiene-1,2-diol
0.2 g/mL in 0.1 M phosphate buffer, 96%
Sinonimo/i:
(1S,2S)-3-Bromo-3,5-cyclohexadiene-1,2-diol
Autenticatiper visualizzare i prezzi riservati alla tua organizzazione & contrattuali
About This Item
Formula empirica (notazione di Hill):
C6H7BrO2
Numero CAS:
Peso molecolare:
191.02
Numero MDL:
Codice UNSPSC:
12352002
ID PubChem:
NACRES:
NA.22
Prodotti consigliati
Saggio
96%
Attività ottica
[α]22/D +20°, c = 1 in methanol
Concentrazione
0.2 g/mL in 0.1 M phosphate buffer
pH
8.5(adjusted to)
Punto di fusione
90-94 °C (lit.)
Gruppo funzionale
bromo
hydroxyl
Temperatura di conservazione
−20°C
Stringa SMILE
O[C@H]1C=CC=C(Br)[C@H]1O
InChI
1S/C6H7BrO2/c7-4-2-1-3-5(8)6(4)9/h1-3,5-6,8-9H/t5-,6+/m0/s1
KLPGXZKAVBGFGF-NTSWFWBYSA-N
Descrizione generale
(1S-cis)-3-Bromo-3,5-cyclohexadiene-1,2-diol is a chiral cis-dienediol employed as a key building block for the preparation of varieties of natural products. It can undergo few chemical reactions like cycloadditions, sigmatropic rearrangements, electrophilic additions, and oxidative cleavage.
Stato fisico
A suspension in phosphate buffer.
Ricostituzione
To recover the pure product from the suspension:
(1)Thaw the frozen suspension and filter the solid. (2) Rinse bottle with a few milliliters of base-washed (aqueous Na2CO3) ethyl acetate. (3) Use the rinsing to wash the solid. (4) Collect solid. (5) To further collect more product from the filtrate: extract filtrate with equal volumes of base-washed (aqueous Na2CO3) ethyl acetate (repeat three times). (6) Dry the ethyl acetate extract over MgSO4. (7) Evaporate the solvent - DO NOT HEAT! (8) Combine solids collected from the suspension and the filtrate. Pure crystals should be stored at -78° C. A suspension of the product in phosphate buffer is stable at 0° C.
(1)Thaw the frozen suspension and filter the solid. (2) Rinse bottle with a few milliliters of base-washed (aqueous Na2CO3) ethyl acetate. (3) Use the rinsing to wash the solid. (4) Collect solid. (5) To further collect more product from the filtrate: extract filtrate with equal volumes of base-washed (aqueous Na2CO3) ethyl acetate (repeat three times). (6) Dry the ethyl acetate extract over MgSO4. (7) Evaporate the solvent - DO NOT HEAT! (8) Combine solids collected from the suspension and the filtrate. Pure crystals should be stored at -78° C. A suspension of the product in phosphate buffer is stable at 0° C.
Codice della classe di stoccaggio
11 - Combustible Solids
Classe di pericolosità dell'acqua (WGK)
WGK 3
Punto d’infiammabilità (°F)
Not applicable
Punto d’infiammabilità (°C)
Not applicable
Dispositivi di protezione individuale
Eyeshields, Gloves, type N95 (US)
Scegli una delle versioni più recenti:
Possiedi già questo prodotto?
I documenti relativi ai prodotti acquistati recentemente sono disponibili nell’Archivio dei documenti.
Medium-scale preparation of useful metabolites of aromatic compounds via whole-cell fermentation with recombinant organisms
Endoma MA, et al.
Organic Process Research & Development, 6(4), 525-532 (2002)
Enzymatic dihydroxylation of aromatics in enantioselective synthesis: expanding asymmetric methodology
Hudlicky T, et al.
Aldrichimica Acta, 32, 35-62 (1999)
Il team dei nostri ricercatori vanta grande esperienza in tutte le aree della ricerca quali Life Science, scienza dei materiali, sintesi chimica, cromatografia, discipline analitiche, ecc..
Contatta l'Assistenza Tecnica.