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383317

Sigma-Aldrich

Zinc acetate

99.99% trace metals basis

Sinonimo/i:

Zn(OAc)2

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About This Item

Formula condensata:
(CH3CO2)2Zn
Numero CAS:
Peso molecolare:
183.48
Numero CE:
Numero MDL:
Codice UNSPSC:
12161600
ID PubChem:
NACRES:
NA.22

Livello qualitativo

Saggio

99.99% trace metals basis

Forma fisica

solid

Impiego in reazioni chimiche

core: zinc
reagent type: catalyst

Impurezze

<0.2% water

Densità

1.84 g/mL at 25 °C (lit.)

Stringa SMILE

CC(O[Zn]OC(C)=O)=O

InChI

1S/2C2H4O2.Zn/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2
DJWUNCQRNNEAKC-UHFFFAOYSA-L

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Descrizione generale

Zinc acetate is primarily utilized as a precursor or catalyst in various synthetic reactions. In organic chemistry, zinc acetate finds application as a reagent in the formation of carbon-carbon bonds. It can facilitate the synthesis of esters, allylic alcohols, and acetals. For example, it can promote the acylation of alcohols, phenols, and amines to form esters, such as the Fischer esterification reaction. Zinc acetate has also been used in the synthesis of metal-organic frameworks (MOFs). MOFs are porous materials consisting of metal ions or clusters coordinated to organic ligands. Zinc acetate can act as a precursor for the formation of MOFs due to its ability to coordinate with organic linkers and form robust networks.

For small scale and high throughput uses, product is also available as ChemBeads (927805)

Applicazioni

Zinc acetate has been used in:
  • Synthesis of layered Zn-arylphosphonates with potential application in sorption, ion exchange or catalysis.
  • Ultrasonic preparation of zinc sulfide nanoparticles coated on silica particles.
  • Synthesis of ZnO/ZnS composites throughion exchange method (1)
  • Fabrication of 3D hierarchical ZnO/ZnSheterojunction branched nanowires for enhanced photoelectrochemical watersplitting (2)
  • Synthesis of Co3O4-decorated ZnO@ZnS core-shellstructures for efficient photocatalytic overall water splitting (3)
  • Synthesis of ZnO photocatalysts (4)

Nota sulla preparazione

Preparation of ZnSe nanostructures upon thermolysis of zinc acetate and selenourea in a mixture of octadecylamine and trioctylphosphine oxide.

Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1

Codice della classe di stoccaggio

11 - Combustible Solids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

dust mask type N95 (US), Eyeshields, Gloves


Certificati d'analisi (COA)

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