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468517

Sigma-Aldrich

3,5-Bis(trifluoromethyl)phenyl isothiocyanate

98%

Sinonimo/i:

1-Isothiocyanato-3,5-bis(trifluoromethyl)benzene

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About This Item

Formula condensata:
(CF3)2C6H3NCS
Numero CAS:
23165-29-9
Peso molecolare:
271.18
Numero MDL:
MFCD00040838
Codice UNSPSC:
12352100
ID PubChem:
24870523
NACRES:
NA.22

Saggio

98%

Indice di rifrazione

n20/D 1.5 (lit.)

P. eboll.

63 °C/1.5 mmHg (lit.)

Densità

1.485 g/mL at 25 °C (lit.)

Stringa SMILE

FC(F)(F)c1cc(cc(c1)C(F)(F)F)N=C=S

InChI

1S/C9H3F6NS/c10-8(11,12)5-1-6(9(13,14)15)3-7(2-5)16-4-17/h1-3H
FXOSSGVJGGNASE-UHFFFAOYSA-N

Categorie correlate

Applicazioni

3,5-Bis(trifluoromethyl)phenyl isothiocyanate has been employed for the following studies:
  • Chemical derivatization of amino-functionalized model surfaces, amino thiolate on Au, amino siloxane on Si, and polyethylene (PE) foils and films.
  • Chemical derivatization of self assembled monolayers of ω-amino-4,4′-terphenyl substituted alkanethiols.
  • Synthesis of ethylene-linked sulfonimidoyl-containing thioureas.
  • Preparation of pyrrolidine-2-carboxylic acid-{2-[3-(3,5-bistrifluoromethylphenyl)thioureido]phenyl}-amide.

Pittogrammi

Skull and crossbones
GHS06

Avvertenze

Danger

Indicazioni di pericolo

H301,H315,H319,H335

Classi di pericolo

Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Organi bersaglio

Respiratory system

Codice della classe di stoccaggio

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

228.2 °F - closed cup

Punto d’infiammabilità (°C)

109 °C - closed cup

Dispositivi di protezione individuale

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Certificati d'analisi (COA)

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Highly diastereo-and enantioselective direct aldol reactions promoted by water-compatible organocatalysts bearing a pyrrolidinyl-camphor structural scaffold.
Tzeng Z-H, et al.
Tetrahedron, 65(5), 2879-2888 (2009)
Paul M Dietrich et al.
Langmuir : the ACS journal of surfaces and colloids, 26(6), 3949-3954 (2010-01-01)
Amino-terminated self-assembled monolayers on gold substrates were studied by X-ray photoelectron spectroscopy (XPS), near-edge X-ray absorption fine structure (NEXAFS) measurements, and atomic force microscopy (AFM). Two different omega-amino-4,4'-terphenyl substituted alkanethiols of the general structure H(2)N-(C(6)H(4))(3)-(CH(2))(n)-SH (ATPn) were used: 2-(4''-amino-1,1':4',1''-terphenyl-4-yl)ethane-1-thiol (n
Marcus Frings et al.
Beilstein journal of organic chemistry, 8, 1443-1451 (2012-09-29)
For the first time, chiral sulfoximine derivatives have been applied as asymmetric organocatalysts. In combination with a thiourea-type backbone the sulfonimidoyl moiety leads to organocatalysts showing good reactivity in the catalytic desymmetrization of a cyclic meso-anhydride and moderate enantioselectivity in
Nora Graf et al.
Analytical and bioanalytical chemistry, 396(2), 725-738 (2009-11-06)
The determination of amino groups on surfaces capable of binding biomolecules is important for the understanding and optimization of technologically relevant coupling processes. In this study, three different types of amino-functionalized model surfaces, amino thiolate on Au, amino siloxane on

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