410497

4-(Dicyanomethylene)-2-methyl-6-(4-dimethylaminostyryl)-4H-pyran

Dye content 98 %

• Sinonimo/i: DCM
• Formula empirica (notazione di Hill): C₁₉H₁₇N₃O
• Numero CAS: 51325-91-8
• Peso molecolare: 303.36
• Numero CE: 257-137-6
• Numero MDL: MFCD00051341
• Codice UNSPSC: 12352103
• ID PubChem: 24865530
• NACRES: NA.23

Proprietà

• Stato: solid
• Livello qualitativo: 200
• Composizione: Dye content, 98%
• Punto di fusione: 215-220 °C (lit.)
• λmax: 468 nm
• Prestazioni di un dispositivo OLED: ITO/Alq₃:DCM/Alq₃/Mg:Ag;
  • Color: red
  • Max. EQE: 1.3 %
  ; ITO/TPD/Alq₃:DCM (10%)/Alq₃/Mg:Ag;
  • Color: red
  • Max. Luminance: 150 Cd/m²
• Stringa SMILE: CN(C)c1ccc(\C=C\C2=CC(\C=C(C)O2)=C(\C#N)C#N)cc1
• InChI: 1S/C19H17N3O/c1-14-10-16(17(12-20)13-21)11-19(23-14)9-6-15-4-7-18(8-5-15)22(2)3/h4-11H,1-3H3/b9-6+; YLYPIBBGWLKELC-RMKNXTFCSA-N

Descrizione

Descrizione generale

4-(Dicyanomethylene)-2-methyl-6-(4-dimethylaminostyryl)-4H-pyran (DCM) is a red laser dye that consists of dicyanomethylene as an electron acceptor and dimethylaniline group as an electron donor. It has a π-conjugated 4H-pyran-4-ylidiene which bridges both the acceptor/donor groups. It can be used as a dopant and also in organic solid state lasers.[1][2]

Applicazioni

DCM can be used as a laser dye to enhance the emission of distributed feedback (DFB) device by FÖrster resonance energy transfer (FRET).[3] It may be used as a capping layer that allows the conversion of blue to red colored emission in organic light emitting diodes (OLED).[4] DCM may also find potential applications in the enhancement of energy transfer of different devices like metal organic frameworks (MOFs),[5] dye sensitized solar cells (DSSCs)[6] and polarity sensors.[7]

Caratteristiche e vantaggi

Voltage-tunable multicolor emission with enhanced luminance (~1000 cd/m²) was observed using varying amounts of DCM dye in a polymer light-emitting diode (PLED).[8]

Informazioni sulla sicurezza

• Pittogrammi: GHS02,GHS07
• Avvertenze: Danger
• Indicazioni di pericolo: H228,H315,H319,H332,H335
• Consigli di prudenza: P210 - P240 - P241 - P302 + P352 - P304 + P340 + P312 - P305 + P351 + P338
• Classi di pericolo: Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Sol. 1 - Skin Irrit. 2 - STOT SE 3
• Organi bersaglio: Respiratory system
• Codice della classe di stoccaggio: 4.1B - Flammable solid hazardous materials
• Classe di pericolosità dell'acqua (WGK): WGK 3
• Punto d’infiammabilità (°F): 109.4 °F - closed cup
• Punto d’infiammabilità (°C): 43 °C - closed cup
• Dispositivi di protezione individuale: Eyeshields, Gloves, type P3 (EN 143) respirator cartridges