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Sigma-Aldrich

Lanthanum(III) nitrate hexahydrate

99.99% trace metals basis

Sinonimo/i:

Nitric acid, lanthanum (III) salt, hexahydrate

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5 G
49,50 €
100 G
203,00 €
500 G
684,00 €

About This Item

Formula condensata:
La(NO3)3 · 6H2O
Numero CAS:
Peso molecolare:
433.01
Numero CE:
Numero MDL:
Codice UNSPSC:
12352302
ID PubChem:
NACRES:
NA.23
Saggio:
99.99% trace metals basis
Stato:
solid

49,50 €


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Livello qualitativo

Saggio

99.99% trace metals basis

Stato

solid

Impiego in reazioni chimiche

reagent type: catalyst
core: lanthanum

Impurezze

≤150.0 ppm Trace Rare Earth Analysis

Punto di fusione

65-68 °C

Stringa SMILE

[La+3].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/La.3NO3.6H2O/c;3*2-1(3)4;;;;;;/h;;;;6*1H2/q+3;3*-1;;;;;;
GJKFIJKSBFYMQK-UHFFFAOYSA-N

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Descrizione generale

Lanthanum(III) nitrate hexahydrate is a transition metal catalyst widely used in many organic transformations. It can be prepared from lanthanum(III) oxide by treatment with N2O4 or nitric acid. It is easy to handle and stable due to the presence of coordinative NO3− moieties. It also finds application in the field of nanomaterial synthesis.

Applicazioni

Lanthanum(III) nitrate hexahydrate can be used as a starting material:
  • For the electrochemical synthesis of a LaMnO3 thin film coating on stainless steel substrates.[1]
  • In the solvothermal process for formation of doped lanthanide oxysulfide, La2O2S, in order to advance possible applications of this material in phosphors, fluorescent display tubes or heat transfer measurement.[2]
  • For the chemoselective catalytic deprotection of acetonides.
  • In the preparation of highly active and nearly neutral lanthanum(III)nitrate alkoxide catalyst.

Caratteristiche e vantaggi

  • High stability
  • Low toxicity
  • Mild reaction condition
  • Chemoselectivity
  • Inexpensive

Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Ox. Sol. 2

Codice della classe di stoccaggio

5.1B - Oxidizing hazardous materials

Classe di pericolosità dell'acqua (WGK)

WGK 2

Dispositivi di protezione individuale

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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The reaction between polyoxometalate (POM) [TBA](12)[WZn{Zn(H(2)O)}(2)(ZnW(9)O(34))(2)] (TBA = tetrabutyl ammonium) and lanthanide (Ln) nitrate (Ln = La, Eu and Tb) in a mixed solvent of CH(3)CN and DMF yielded three noncentrosymmetric diamondoid Ln-POM solid materials, {[Ln(2)(DMF)(8)(H(2)O)(6)][ZnW(12)O(40)]}·4DMF (Ln-POM; Ln = La
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