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234893

Sigma-Aldrich

Ethyl methacrylate

contains 15-20 ppm monomethyl ether hydroquinone as inhibitor, 99%

Sinonimo/i:

2-Methyl-2-propenoic acid

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About This Item

Formula condensata:
CH2=C(CH3)COOC2H5
Numero CAS:
Peso molecolare:
114.14
Beilstein:
471201
Numero CE:
Numero MDL:
Codice UNSPSC:
12162002
ID PubChem:
NACRES:
NA.25

Densità del vapore

>3.9 (vs air)

Tensione di vapore

15 mmHg ( 20 °C)

Saggio

99%

Forma fisica

liquid

Temp. autoaccensione

771 °F

contiene

15-20 ppm monomethyl ether hydroquinone as inhibitor

Indice di rifrazione

n20/D 1.413 (lit.)

P. eboll.

118-119 °C (lit.)

Densità

0.917 g/mL at 25 °C (lit.)

Temperatura di conservazione

2-8°C

Stringa SMILE

CCOC(=O)C(C)=C

InChI

1S/C6H10O2/c1-4-8-6(7)5(2)3/h2,4H2,1,3H3
SUPCQIBBMFXVTL-UHFFFAOYSA-N

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Descrizione generale

Ethyl methacrylate (EMA) is a monomer commonly used in the field of polymer industries. It is an ester of methacrylic acid and ethanol and is a colorless liquid with a characteristic odor. EMA is widely used in the production of various polymers such as poly(methyl methacrylate) (PMMA), poly(ethyl acrylate) (PEA), and ethylene-EMA (EE). These polymers find their application in various fields, including medical implant devices, packaging, paper coatings, textile coatings, emulsion polymers, and plastics.

Ethyl methacrylate is a readily polymerizable monomer used for certain types of acrylic resins. The monomethyl ether hydroxyl quinone present in it is an inhibitor that prevents polymerization.

Applicazioni

Ethyl methacrylate (EMA) can be used as a monomer in the following applications:
  • To synthesize artificial nanosized latexes of poly(styrene-co-methyl methacrylate) or poly(styrene-co-ethyl methacrylate), which are in producing drug-releasing films.
  • In the production of additive-manufactured methacrylate-based resins used in dentistry.
  • In the synthesis of a star-shaped block copolymer electrolyte for all-solid-state lithium batteries.
  • In the synthesis of a copolymer used as a matrix for semiconductor nanoparticles, which is crucial for the formation of a stable matrix for the quantum dots-copolymer composite material used in optoelectronic applications.
It can also be used to prepare copolymers of EMA on waxy maize starch and hydroxypropyl starch, the potential application of these copolymers are as excipients for compressed non-disintegrating matrix tablets. It may be used to study reactions of n-butyl acrylate and EMA with ozone in the gas phase.

Pittogrammi

FlameExclamation mark

Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Organi bersaglio

Respiratory system

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 1

Punto d’infiammabilità (°F)

66.2 °F - closed cup

Punto d’infiammabilità (°C)

19 °C - closed cup

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


Certificati d'analisi (COA)

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Reactions of n-butyl acrylate and ethyl methacrylate with ozone in the gas phase, Computational and Theoretical Chemistry
Sun Y, et al.
Computational & Theoretical Chemistry, 1039, 33-39 (2014)
Elena Torres et al.
Polymers, 12(8) (2020-08-06)
We aimed to study the distribution of hydroxyapatite (HA) and halloysite nanotubes (HNTs) as fillers and their influence on the hydrophobic character of conventional polymers used in the biomedical field. The hydrophobic polyester poly (ε-caprolactone) (PCL) was blended with its
Mengwei Pi et al.
Colloids and surfaces. B, Biointerfaces, 78(2), 193-199 (2010-03-30)
The nanoparticles composed of polystyrene core and poly[2-(diethylamino)ethyl methacrylate] (PDEA) hairy shell were used as colloidal templates for in situ silica mineralization, allowing the well-controlled synthesis of hybrid silica core-shell nanoparticles with raspberry-like morphology and hollow silica nanoparticles by subsequent
K C Gupta et al.
Biomacromolecules, 2(1), 239-247 (2001-12-26)
The graft copolymerization of acrylonitrile and ethyl methacrylate from their binary mixtures onto cellulose has been carried out in the presence of Ce(IV) ions in acidic media at 30 +/- 0.1 degrees C. The graft copolymerization has shown an increasing
M B Abou-Donia et al.
Journal of toxicology and environmental health. Part A, 59(2), 97-118 (2000-02-01)
Ethyl methacrylate (ethyl 2-methyl-2-propenoate, EMA) has been implicated in the development of neurologic impairment following occupational exposure. The potential of EMA to produce neurotoxicity was investigated in adult male Sprague-Dawley rats in two experiments. In the first experiment, animals were

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