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163015
Thallium(III) nitrate trihydrate
Sinonimo/i:
TTN, Thallium trinitrate
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25 G
309,00 €
100 G
1.030,00 €
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Cambia visualizzazione
25 G
309,00 €
100 G
1.030,00 €
About This Item
Formula condensata:
Tl(NO3)3 · 3H2O
Numero CAS:
Peso molecolare:
444.44
Numero CE:
Numero MDL:
Codice UNSPSC:
12161600
ID PubChem:
NACRES:
NA.22
Prodotti consigliati
Livello qualitativo
Impiego in reazioni chimiche
core: thallium
reagent type: catalyst
Punto di fusione
102-105 °C (lit.)
Stringa SMILE
O.O.O.[Tl+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O
InChI
1S/3NO3.3H2O.Tl/c3*2-1(3)4;;;;/h;;;3*1H2;/q3*-1;;;;+3
ZCPIKMRXMBJLCP-UHFFFAOYSA-N
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Categorie correlate
Applicazioni
Reagent for the rapid oxidation of styrene derivatives to carbonyl compounds,[1] for the regioselective ring expansion of cyclic aralkyl ketones via oxidative rearrangement,[2] for the selective hydrolysis of thioacetals to carbonyl compounds[3] and for a general synthetic method to 19-norsteroids.[4] Mediates ring contraction of cyclic ketones to a series of trans-fused 10-methyl-2-decalones.[5]
Avvertenze
Danger
Indicazioni di pericolo
Consigli di prudenza
Classi di pericolo
Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Chronic 2 - STOT RE 2
Codice della classe di stoccaggio
5.1B - Oxidizing hazardous materials
Classe di pericolosità dell'acqua (WGK)
WGK 3
Punto d’infiammabilità (°F)
Not applicable
Punto d’infiammabilità (°C)
Not applicable
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Journal of the American Chemical Society, 98, 3037-3037 (1976)
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Articoli
Oxidation and reduction reactions are some of the most common transformations encountered in organic synthesis
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Thallium(III) nitrate trihydrate(CASRN:13453-38-8)ですが、SDSでは毒劇法に非該当の記載です。一方、WEBでは毒劇法の劇物の記載です。どちらが正しいのでしょうか。 水和物を原体とするか製剤とするかで判断が異なるのでしょうか。
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