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等级
purum p.a.
方案
≥98.0% (calc. based on dry substance, T)
表单
powder
反应适用性
reagent type: oxidant
杂质
≤3% water
pH值（酸碱度）
6.0-9.5 (25 °C, 106.4 g/L)
mp
236 °C (lit.)
溶解性
alcohol: soluble(lit.)
water: soluble(lit.)
痕量阴离子
chloride (Cl-): ≤50 mg/kg
sulfate (SO42-): ≤200 mg/kg
痕量阳离子
Ca: ≤100 mg/kg
Cd: ≤50 mg/kg
Co: ≤50 mg/kg
Cu: ≤50 mg/kg
Fe: ≤50 mg/kg
K: ≤500 mg/kg
Na: ≤100 mg/kg
Ni: ≤50 mg/kg
Pb: ≤50 mg/kg
Zn: ≤50 mg/kg
SMILES字符串
[Li+].[O-]Cl(=O)(=O)=O
InChI
1S/ClHO4.Li/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1
InChI key
MHCFAGZWMAWTNR-UHFFFAOYSA-M
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一般描述
Lithium perchlorate (LiClO4) is a colorless lithium salt. Upon crystallization from its aqueous solution, it affords lithium perchlorate trihydrate (LiClO4.3H2O). It can be synthesized by reacting lithium chloride with perchloric acid.
应用
Lithium perchlorate (LiClO4) may be used as a catalyst in the synthesis of bis(indolyl)methanes and in the Baylis-Hillman coupling reaction of α,β-unsaturated carbonyl compounds with aldehydes.
警示用语：
Danger
危险分类
Acute Tox. 4 Oral - Eye Dam. 1 - Ox. Sol. 2 - Skin Corr. 1A - STOT SE 3
靶器官
Respiratory system
储存分类代码
5.1A - Strongly oxidizing hazardous materials
WGK
WGK 1
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Lithium perchlorate-accelerated Baylis-Hillman reactions.
Kawamura M and Kobayashi S.
Tetrahedron Letters, 40(8), 1539-1542 (1999)
Lithium perchlorate catalyzed reactions of indoles: An expeditious synthesis of bis (indolyl) methanes.
Yadav JS, et al.
Synthesis, 2001(5), 0783-0787 (2001)
Increased T(c) in electrolyte-gated cuprates.
Anoop Singh Dhoot et al.
Advanced materials (Deerfield Beach, Fla.), 22(23), 2529-2533 (2010-05-07)
Electrochemical enol ether/olefin cross-metathesis in a lithium perchlorate/nitromethane electrolyte solution.
Teppei Miura et al.
Angewandte Chemie (International ed. in English), 45(9), 1461-1463 (2006-01-28)
S Selvasekarapandian et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 65(5), 1234-1240 (2006-07-11)
The polymer electrolytes composed of poly(vinyl acetate) (PVAc) with various stoichiometric ratios of lithium perchlorate (LiClO(4)) salt have been prepared by solution casting method. The techniques Fourier transform infra-red (FTIR) and Laser Raman spectroscopy have been used to monitor polymer-salt
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