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Merck

311375

Sigma-Aldrich

氯化锑(III)

ACS reagent, ≥99.0%

别名:

三氯化锑

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About This Item

线性分子式:
SbCl3
CAS号:
分子量:
228.12
EC 号:
MDL编号:
UNSPSC代码:
12352302
eCl@ss:
38080204
PubChem化学物质编号:
NACRES:
NB.24

等级

ACS reagent

质量水平

蒸汽密度

7.9 (vs air)

蒸汽压

1 mmHg ( 49 °C)

方案

≥99.0%

表单

powder, crystals or chunks

反应适用性

reagent type: catalyst
core: antimony

杂质

≤0.05% insol. CHCl3

mp

73.4 °C (lit.)

痕量阴离子

sulfate (SO42-): ≤0.005%

痕量阳离子

As: ≤0.02%
Ca: ≤0.005%
Cu: ≤0.001%
Fe: ≤0.002%
K: ≤0.01%
Na: ≤0.02%
Pb: ≤0.005%

SMILES字符串

Cl[Sb](Cl)Cl

InChI

1S/3ClH.Sb/h3*1H;/q;;;+3/p-3

InChI key

FAPDDOBMIUGHIN-UHFFFAOYSA-K

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应用

氯化锑(III)(SbCl3)是一种路易斯酸催化剂,用于各种有机反应,如聚合、Friedel-Crafts 酰化、NaBH4 还原、环氧化合物开环、三烷基醚裂解、Biginelli 反应和氯化反应。它也被用作合成其他锑盐的前体。

象形图

CorrosionEnvironment

警示用语:

Danger

危险声明

危险分类

Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B

储存分类代码

8A - Combustible corrosive hazardous materials

WGK

WGK 2

闪点(°F)

Not applicable

闪点(°C)

Not applicable


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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访问文档库

Synthesis, structural characterization and cytotoxicity of the antimony (III) chloride complex with N, N-dicyclohexyldithiooxamide.
Ozturk II, et al.
Polyhedron, 52, 1403-1410 (2013)
Antimony (III) chloride-catalyzed ring opening of epoxides with anilines.
Singh MC and Peddinti RK.
Tetrahedron Letters, 48(41), 7354-7357 (2007)
Antimony (III) chloride-catalysed Biginelli reaction: a versatile method for the synthesis of dihydropyrimidinones through a different reaction mechanism
Cepanec I, et al.
Tetrahedron, 63(48), 11822-11827 (2007)
Nucleic acid related compounds. 79. Efficient conversions of thioethers to. alpha.-fluoro thioethers with DAST or DAST/antimony (III) chloride.
Robins MJ and Wnuk SF.
The Journal of Organic Chemistry, 58(15), 3800-3800 (1993)
N Schaumlöffel et al.
Mutagenesis, 13(3), 281-286 (1998-06-27)
Data on the mechanism of antimony genotoxicity is scarce. Arsenic and antimony are proposed to share some toxicological features. Thus comparative and combined experiments with As(III) and Sb(III) were performed to gain a deeper knowledge of the mechanism of antimony

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