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Merck

901784

Sigma-Aldrich

Nitro-grela 1st generation

≥95%

别名:

Dichloro(2-isopropoxy-5-nitrophenylmethylene)(tricyclohexylphosphine)ruthenium(II)

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About This Item

经验公式(希尔记法):
C28H44Cl2NO3PRu
分子量:
645.60
分類程式碼代碼:
12352202

化驗

≥95%

形狀

powder

反應適用性

core: ruthenium
reagent type: catalyst

存貨情形

available only in USA

mp

>300 °C

儲存溫度

2-8°C

應用

Nitro-grela 1st generation is good for olefin metathesis for en-yn reactions.

法律資訊

Sold in collaboration with Apeiron Synthesis, Inc. Research quantities are 100 g / customer / year. For quantities that exceed the research limit, please contact the supplier at www.apeiron-synthesis.com.
PCT/EP2003/011222

象形圖

Flame

訊號詞

Danger

危險聲明

危險分類

Self-react. C

儲存類別代碼

5.2 - Organic peroxides and self-reacting hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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Anna Michrowska et al.
Journal of the American Chemical Society, 126(30), 9318-9325 (2004-07-30)
The design, synthesis, stability, and catalytic activity of nitro-substituted Hoveyda-Grubbs metathesis catalysts are described. The highly active and stable meta- and para-substituted complexes are attractive from a practical point of view. These catalysts operate in very mild conditions and can

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