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Merck

108170

Sigma-Aldrich

硝基甲烷

reagent grade, 96%

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About This Item

经验公式(希尔记法):
CH3NO2
CAS号:
分子量:
61.04
Beilstein:
1698205
EC號碼:
MDL號碼:
分類程式碼代碼:
12352102
PubChem物質ID:

等級

reagent grade

蒸汽密度

2.1 (vs air)

蒸汽壓力

2.7 mmHg

化驗

96%

形狀

liquid

自燃溫度

784 °F

expl. lim.

7.3 %, 33 °F

折射率

n20/D 1.382 (lit.)

bp

101.2 °C (lit.)

mp

−29 °C (lit.)

密度

1.127 g/mL at 25 °C (lit.)

SMILES 字串

C[N+]([O-])=O

InChI

1S/CH3NO2/c1-2(3)4/h1H3

InChI 密鑰

LYGJENNIWJXYER-UHFFFAOYSA-N

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其他說明

A -D suffix exists for administrative purposes only.
All -D packages are 100% the same product, same quality, same specification as the package sizes previously sold without a -D.

訊號詞

Warning

危險分類

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 3 - Repr. 2

儲存類別代碼

4.1A - Other explosive hazardous materials

水污染物質分類(WGK)

WGK 2

閃點(°F)

95.0 °F - closed cup

閃點(°C)

35 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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分析证书(COA)

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The catalytic chemistry of nitromethane over Co-ZSM5 and other catalysts in connection with the methane-NOxSCR reaction.
Cowan AD, et al.
J. Catal., 176(2), 329-343 (1998)
Metal ion encapsulation: cobalt cages derived from polyamines, formaldehyde, and nitromethane.
Geue RJ, et al.
Journal of the American Chemical Society, 106(19), 5478-5488 (1984)
Benedek Vakulya et al.
Organic letters, 7(10), 1967-1969 (2005-05-07)
Cinchona alkaloid-derived chiral bifunctional thiourea organocatalysts were synthesized and applied in the Michael addition between nitromethane and chalcones with high ee and chemical yields.
Wenguo Yang et al.
Chemistry, an Asian journal, 7(4), 771-777 (2012-02-10)
Through the cleavage of the C-C bond, the first catalytic tandem conjugate addition-elimination reaction of Morita-Baylis-Hillman C adducts has been presented. Various S(N)2'-like C-, S-, and P-allylic compounds could be obtained with exclusive E configuration in good to excellent yields.
Eagleson M.
Concise Encyclopedia Chemistry, 696-696 (1994)

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