8.20528

Diphenylamine

for synthesis

• 别名: Diphenylamine, N-Phenylaniline
• 线性分子式: (C₆H₅)₂NH
• CAS号: 122-39-4
• 分子量: 169.22
• MDL號碼: MFCD00003014
• 分類程式碼代碼: 12352116
• 酶委員會索引編號: 204-539-4
• NACRES: NA.22

属性

• 蒸汽壓力: 0.0003 hPa ( 20 °C)
• 品質等級: 200
• 化驗: ≥99.0% (GC)
• 形狀: solid
• 自燃溫度: 630 °C (DIN 51794)
• 效力: 1120 mg/kg LD₅₀, oral (Rat); >5000 mg/kg LD₅₀, skin (Rabbit)
• bp: 302 °C/1013 hPa
• mp: 53-54 °C
• 轉變溫度: flash point 153 °C (DIN 51758)
• 溶解度: 0.05 g/L
• 密度: 1.16 g/cm³ at 20 °C
• 體積密度: 610 kg/m³
• 儲存溫度: no temp limit
• InChI: 1S/C12H11N/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12/h1-10,13H
• InChI 密鑰: DMBHHRLKUKUOEG-UHFFFAOYSA-N

说明

應用

• Design of hole transport materials: New small derivatives of 2,2′-bithiophene, possibly involving Diphenylamine as a building block, were rationally designed to improve the performance of perovskite solar cells, demonstrating Diphenylamine′s role in advancing photovoltaic technology (Adadi et al., 2024).
• High-efficiency hyperfluorescent OLEDs: Diphenylamine may be implicated in the development of hybridized local and charge transfer dendrimers, aimed at achieving near-unity exciton utilization in solution-processed OLEDs, highlighting its potential in high-performance electronic displays (Yin et al., 2024).
• Chemical detection technologies: A benzoxazole-triphenylamine conjugated fluorogenic probe was developed for the specific detection of sarin gas mimic diethylchlorophosphate, illustrating Diphenylamine′s utility in sensitive and specific chemical sensors (Sultana et al., 2024).
• Electrochemiluminescence emitters: Diphenylamine-based emitters were tailored for efficient electrochemiluminescence, employing tripropylamine as a co-reactant, contributing to the field of electrochemical sensors and displays (Morgan et al., 2023).
• Near-infrared fluorophores development: Research on chlorinated rylenecarboximide fluorophores, potentially involving Diphenylamine, focused on efficient near-infrared applications, which are critical for advanced imaging and diagnostic techniques (Wu et al., 2023).

分析報告

Assay (GC, area%): ≥ 99.0 % (a/a)
Melting range (lower value): ≥ 52 °C
Melting range (upper value): ≤ 55 °C
Identity (IR): passes test

安全信息

• 象形圖: GHS06,GHS08,GHS09
• 訊號詞: Danger
• 危險聲明: H301 + H311 + H331,H373,H410
• 防範說明: P273 - P280 - P301 + P310 - P302 + P352 + P312 - P304 + P340 + P311 - P314
• 危險分類: Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2
• 標靶器官: Kidney,Liver,spleen
• 儲存類別代碼: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• 水污染物質分類（WGK）: WGK 3