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Merck

00848

Sigma-Aldrich

(1R,4S)-顺式-4-乙酰氧基-2-环戊烯-1-醇

≥98.0% (sum of enantiomers, GC)

别名:

(1S,4R)-顺式-4-羟基-2-环戊烯基乙酸酯

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About This Item

经验公式(希尔记法):
C7H10O3
CAS号:
分子量:
142.15
Beilstein:
4350633
MDL號碼:
分類程式碼代碼:
12352108
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

≥98.0% (sum of enantiomers, GC)

光學活性

[α]20/D −67±2°, c = 2.3% in chloroform

mp

49-51 °C

SMILES 字串

CC(=O)O[C@H]1C[C@@H](O)C=C1

InChI

1S/C7H10O3/c1-5(8)10-7-3-2-6(9)4-7/h2-3,6-7,9H,4H2,1H3/t6-,7+/m0/s1

InChI 密鑰

IJDYOKVVRXZCFD-NKWVEPMBSA-N

應用

(1R,4S)-cis-4-Acetoxy-2-cyclopenten-1-ol can be used as a reactant in the total synthesis of Bartlett′s brefeldin intermediate, spinosyn A analogs, (+)-7-deaza-5′-noraristeromycin, (±) strychnine and the Wieland-Gumlich aldehyde.

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves, type N95 (US)


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Asymmetric Total Syntheses of (-)-and (+)-Strychnine and the Wieland-Gumlich Aldehyde
Knight SD, et al.
Journal of the American Chemical Society, 117(21), 5776-5788 (1995)
A new approach to (+)-brefeldin A via a nickel-catalyzed coupling reaction of cyclopentenyl acetate and lithium 2-furylborate
Kobayashi Y, et al.
Tetrahedron Letters, 37(34), 6125-6128 (1996)
Synthesis of novel spinosyn A analogues by Pd-mediated transformations
Tietze LF, et al.
Chemistry?A European Journal , 13(30), 8543-8563 (2007)
(+)-7-Deaza-5 `-noraristeromycin as an anti-trypanosomal agent
Seley KL, et al.
Journal of Medicinal Chemistry, 40(4), 622-624 (1997)

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