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品質等級
化驗
98%
形狀
powder
反應適用性
reagent type: oxidant
mp
210-215 °C (dec.) (lit.)
儲存溫度
2-8°C
SMILES 字串
ClC1=C(Cl)C(=O)C(C#N)=C(C#N)C1=O
InChI
1S/C8Cl2N2O2/c9-5-6(10)8(14)4(2-12)3(1-11)7(5)13
InChI 密鑰
HZNVUJQVZSTENZ-UHFFFAOYSA-N
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應用
2,3-二氯-5,6-二氰基对苯醌(DDQ)可以用作:
- 各类化合物的脱保护剂,例如硫缩醛、乙缩醛和缩酮。
- 由亚胺和炔烃或烯烃合成喹啉的电子转移试剂。
- 苄基和烯丙基C−H官能化的有效试剂。
- 合成官能化呋喃和苯并呋喃的氧化剂。
- 结合Ph3P有效合成1,2-苯并恶唑类化合物的试剂。
訊號詞
Danger
危險聲明
危險分類
Acute Tox. 3 Oral
安全危害
儲存類別代碼
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
水污染物質分類(WGK)
WGK 3
閃點(°F)
Not applicable
閃點(°C)
Not applicable
個人防護裝備
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
历史批次信息供参考:
其他客户在看
Solvent-Free One-Step Photochemical Hydroxylation of Benzene Derivatives by the Singlet Excited State of 2, 3-Dichloro-5, 6-dicyano-p-benzoquinone Acting as a Super Oxidant.
Chemistry?A European Journal , 21(7), 2855-2861 (2015)
Deprotection of benzyl ethers using 2, 3-dichloro-5, 6-dicyano-p-benzoquinone (DDQ) under photoirradiation.
Tetrahedron Letters, 46(43), 7307-7309 (2005)
Farmaco (Societa chimica italiana : 1989), 57(12), 993-997 (2003-02-05)
Nucleosides have been of great interest since their strong antiviral activities were discovered. 1,3-Oxathiolane ring system has been known for many years, but it is in recent years that the ring has been used as the sugar ring in nucleoside
Predictive model for oxidative C-H bond functionalization reactivity with 2, 3-dichloro-5, 6-dicyano-1, 4-benzoquinone.
Journal of the American Chemical Society, 139(49), 17935-17944 (2017)
DDQ-mediated formation of carbon? carbon bonds: Oxidation of imines
Tetrahedron, 49, 10157-10157 (1993)
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