805041

2-(三甲硅基)-2-环己烯-1-酮

• 经验公式（希尔记法）: C₉H₁₆OSi
• CAS号: 72162-99-3
• 分子量: 168.31
• MDL编号: MFCD11502410
• UNSPSC代码: 12352100
• PubChem化学物质编号: 329768917
• NACRES: NA.22

属性

• 描述: Fp: 15.8°F
• 质量水平: 100
• 表单: liquid
• 折射率: n20/D 1.4524
• 密度: 0.8680 g/mL at 25 °C
• 官能团: ketone
• 储存温度: −20°C
• SMILES字符串: O=C1C([Si](C)(C)C)=CCCC1
• InChI: 1S/C9H16OSi/c1-11(2,3)9-7-5-4-6-8(9)10/h7H,4-6H2,1-3H3
• InChI key: SXGCQSJRVVKTOH-UHFFFAOYSA-N

说明

一般描述

2-(Trimethylsilyl)-2-cyclohexen-1-one is a silyl enone.

应用

The following silyl enone can be converted into a highly useful cyclohexyne precursor as reported by the Garg and DuBois groups. The resulting silyltriflate adduct can be subjected to various dienes and dipolarophiles in the presence of Cesium Fluoride.

其他说明

Cycloadditions of Cyclohexynes and Cyclopentyne

Modular synthesis of the pentacyclic core of batrachotoxin and select batrachotoxin analogue designs

安全信息

• 象形图: GHS02,GHS07
• 警示用语：: Warning
• 危险声明: H228,H302
• 预防措施声明: P210 - P301 + P312 + P330 - P370 + P378
• 危险分类: Acute Tox. 4 Oral - Flam. Sol. 2
• 储存分类代码: 4.1B - Flammable solid hazardous materials
• WGK: WGK 3
• 闪点(°F): 15.8 °F
• 闪点(°C): -9 °C