跳转至内容
Merck

230200

Sigma-Aldrich

硼氢化锂 溶液

2.0 M in THF

别名:

Lithium boron hydride, Lithium hydroborate

登录查看公司和协议定价


About This Item

线性分子式:
LiBH4
CAS号:
分子量:
21.78
MDL號碼:
分類程式碼代碼:
12352302
PubChem物質ID:
NACRES:
NA.22

形狀

liquid

品質等級

反應適用性

reagent type: reductant

濃度

2.0 M in THF

密度

0.896 g/mL at 25 °C

SMILES 字串

[Li+].[H][B-]([H])([H])[H]

InChI

1S/BH4.Li/h1H4;/q-1;+1

InChI 密鑰

UUKMSDRCXNLYOO-UHFFFAOYSA-N

正在寻找类似产品? 访问 产品对比指南

應用

反应物用于:
  • 镓、铟、铼和锌三(巯基咪唑基)氢硼酸配合物的制备
  • 机械化学复分解反应
  • 非催化水解制氢
  • 大型金单层保护簇的生长
  • 阴离子取代反应
  • 脱氢反应
硼氢化锂溶液 (2M in THF) 分别用于 5-亚苄基-2,4-噻唑烷二酮类和 5-亚苄基-4-氧代-2-噻唑烷二酮类的还原,并分别生成 5-苄基-2,4-噻唑烷二酮类和 5-苄基-4-氧代-2-噻唑烷二酮类。

包裝

推荐将25毫升安全/密封瓶作为一次性使用的瓶子。重复穿刺可能会导致产品性能下降。

法律資訊

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

訊號詞

Danger

危險分類

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1

標靶器官

Central nervous system, Respiratory system

安全危害

儲存類別代碼

4.3 - Hazardous materials which set free flammable gases upon contact with water

水污染物質分類(WGK)

WGK 2

閃點(°F)

-0.4 °F - closed cup

閃點(°C)

-18 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


分析证书(COA)

输入产品批号来搜索 分析证书(COA) 。批号可以在产品标签上"批“ (Lot或Batch)字后找到。

已有该产品?

在文件库中查找您最近购买产品的文档。

访问文档库

Regiospecific reduction of 5-benzylidene-2, 4-thiazolidinediones and 4-oxo-2-thiazolidinethiones using lithium borohydride in pyridine and tetrahydrofuran.
Giles RG
Tetrahedron, 56(26), 4531-4537 (2000)
Pascal Martelli et al.
The journal of physical chemistry. A, 114(37), 10117-10121 (2010-09-03)
The hydrogen dynamics in solid and in liquid LiBH4 was studied by means of incoherent quasielastic neutron scattering. Rotational jump diffusion of the BH4- subunits on the picosecond scale was observed in solid LiBH4. The characteristic time constant is significantly
Piter S Miedema et al.
Physical chemistry chemical physics : PCCP, 14(16), 5581-5587 (2012-03-20)
X-Ray Raman Spectroscopy (XRS) is used to study the electronic properties of bulk lithium borohydride (LiBH(4)) and LiBH(4) in porous carbon nano-composites (LiBH(4)/C) during dehydrogenation. The lithium (Li), boron (B) and carbon (C) K-edges are studied and compared with calculations
Prabhat Arya et al.
Journal of combinatorial chemistry, 6(1), 54-64 (2004-01-13)
A diversity-oriented solution and solid-phase synthesis of tetrahydroquinoline-based tricyclic derivatives has been achieved from enantiomerically pure, natural product-like bicyclic scaffold. The solution synthesis of enantiopure bicyclic scaffold was developed by asymmetric hetero Michael reaction. Our approach for the synthesis of
Matthew S Wellons et al.
Nanotechnology, 20(20), 204022-204022 (2009-05-08)
The addition of catalysts to complex hydrides is aimed at enhancing the hydrogen absorption desorption properties. Here we show that the addition of carbon nanostructure C60 to LiBH4 has a remarkable catalytic effect, enhancing the uptake and release of hydrogen.

我们的科学家团队拥有各种研究领域经验,包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.

联系技术服务部门