804320

Potassium 4-ethoxycarbonylbenzoyltrifluoroborate

• 经验公式（希尔记法）: C₁₀H₉BF₃KO₃
• CAS号: 1622923-40-3
• 分子量: 284.08
• MDL编号: MFCD29037014
• UNSPSC代码: 12352103
• PubChem化学物质编号: 329768861
• NACRES: NA.22

属性

• 表单: powder
• 质量水平: 100
• mp: 228.00 °C
• SMILES字符串: O=C(B(F)(F)F)C1=CC=C(C(OCC)=O)C=C1.[K]
• InChI: 1S/C10H9BF3O3.K.H/c1-2-17-10(16)8-5-3-7(4-6-8)9(15)11(12,13)14;;/h3-6H,2H2,1H3;;
• InChI key: YXYMQBSRJGUKGK-UHFFFAOYSA-N

说明

应用

Acyltrifluroborates (KATs) are bench, air, and moisture stable reagents for rapid, chemoselective amide bond formations with hydroxylamines. These amide bond forming reactions proceed under aqueous conditions, without the need for coupling reagents or protecting groups. This product was introduced in collaboration with the Bode Research Group

其他说明

Amide-Forming Ligation of Acyltrifluoroborates and Hydroxylamines in Water

Rapid Ligations with Equimolar Reactants in Water with the Potassium Acyltrifluoroborate (KAT) Amide Formation

Synthesis of Chemically and Configurationally Stable Monofluoro Acylboronates: Effect of Ligand Structure on their Formation; Properties; and Reactivities

安全信息

• 象形图: GHS07
• 警示用语：: Warning
• 危险声明: H315,H319,H335
• 预防措施声明: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• 危险分类: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 靶器官: Respiratory system
• 储存分类代码: 11 - Combustible Solids
• WGK: WGK 3
• 闪点(°F): Not applicable
• 闪点(°C): Not applicable