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质量水平
方案
≥95.0% (sum of enantiomers, GC)
表单
liquid
旋光性
[α]20/D −225±5°, c = 10% in diethyl ether
沸点
171-174 °C (lit.)
密度
0.844 g/mL at 20 °C (lit.)
储存温度
2-8°C
SMILES字符串
CC(C)[C@H]1CC=C(C)C=C1
InChI
1S/C10H16/c1-8(2)10-6-4-9(3)5-7-10/h4-6,8,10H,7H2,1-3H3/t10-/m1/s1
InChI key
OGLDWXZKYODSOB-SNVBAGLBSA-N
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一般描述
(R)-(-)-α-水芹烯是一种单萜衍生物。
应用
(R)-(-)-α-水芹烯可与2-萘基乙炔羧酸进行[4+2]环加成反应形成手性二烯，其可作为铑催化的不对称加成反应的配体。 它可用于合成（1S，5R）-5-（1-甲基乙基）-2-亚甲基-3-环己烯-1-基氢过氧化物，还原形式为 反式-yabunikkeol。
警示用语：
Danger
危险分类
Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Flam. Liq. 3 - Skin Sens. 1B
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
113.0 °F - closed cup
闪点(°C)
45 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
其他客户在看
Chiral diene ligands for asymmetric catalysis.
Hayashi T.
Aldrichimica Acta, 42(2), 31-38 (2009)
Intrazeolite photo-oxygenation of (R)-(-)-a-phellandrene.
Stratakis M and Sofikiti N.
J. Chem. Res. (M), 2002(8), 374-375 (2002)
Kazuhiro Okamoto et al.
Organic letters, 10(19), 4387-4389 (2008-09-06)
Chiral dienes possessing the bicyclo[2.2.2]octadiene framework were prepared readily through the [4 + 2] cycloaddition of ( R)-alpha-phellandrene with methyl propiolate as the key step. Diene 9, substituted with a tertiary alcohol on one of the two double bonds, is
S Foss et al.
Systematic and applied microbiology, 21(2), 237-244 (1998-08-15)
Four pseudomonad strains 51Men, 54Pin, 62Car and 65Phen were recently isolated on the monoterpenes (+)-menthene, alpha-pinene, 2-carene and alpha-phellandrene as sole carbon source and nitrate as electron acceptor. These bacteria were characterised. The motile, mesophilic, Gram-negative rods had a strictly
Huai-sheng Hu et al.
Zhong yao cai = Zhongyaocai = Journal of Chinese medicinal materials, 32(1), 67-70 (2009-05-19)
The chemical constituents and antimicrobial activity of the essential oil from Acanthopanax brachypus were studied. The essential oil was extracted from the stem of A. brachypus by steam distillation, and its antimicrobial activity was tested in vitro. The chemical constituents
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