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About This Item
经验公式（希尔记法）:
C32H22O2
CAS号:
分子量:
438.52
MDL號碼:
分類程式碼代碼:
12352005
PubChem物質ID:
NACRES:
NA.22
推荐产品
化驗
97%
光學活性
[α]20/D -314°, c = 1 in chloroform
mp
199-203 °C
SMILES 字串
Oc1c(c(cc2ccccc12)-c3ccccc3)-c4c(O)c5ccccc5cc4-c6ccccc6
InChI
1S/C32H22O2/c33-31-25-17-9-7-15-23(25)19-27(21-11-3-1-4-12-21)29(31)30-28(22-13-5-2-6-14-22)20-24-16-8-10-18-26(24)32(30)34/h1-20,33-34H
InChI 密鑰
NDTDVKKGYBULHF-UHFFFAOYSA-N
應用
(S)-VANOL 是一种拱形联芳基配体，可用于合成配位配合物，例如（dppe）Pt（S-VANOL）[dppe =双（二苯基膦基）乙烷]和（S,S-chiraphos）Pt （S-VANOL）[Chiraphos＝2，3-双（二苯基膦基）丁烷]。
VANOL 已被证明是催化不对称 Diels-Alder、亚胺羟醛和叠氮化反应的出色配体。
訊號詞
Danger
危險分類
Aquatic Chronic 4 - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
11 - Combustible Solids
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
個人防護裝備
dust mask type N95 (US), Eyeshields, Gloves
Synthesis and characterization of chiral diphosphine platinum (II) VANOL and VAPOL complexes.
Becker JJ, et al.
Organometallics, 22(16), 3245-3249 (2003)
Bao. J. et al.
Journal of the American Chemical Society, 118, 3392-3392 (1996)
Su Yu et al.
Organic letters, 7(3), 367-369 (2005-01-28)
[reaction: see text] In an effort to develop a synthesis of the VAPOL ligand that avoids the use of a chromium carbene complex, a route was examined that involved the annulation of a naphthalene carboxamide via the method of Snieckus.
Yu Zhang et al.
Organic letters, 5(11), 1813-1816 (2003-05-24)
[reaction: see text] A copper-mediated deracemization of the vaulted biaryl ligands VANOL and VAPOL can be readily achieved in the presence of (-)-spartiene. The optimal procedure involves the in situ generation of copper(II) and leads to the reproducible formation of
相关内容
The research areas of interest to the Wulff group include enantioselective catalysis, mechanisms of asymmetric catalysis, macromolecular chemistry, Fischer carbene complexes in organic synthesis and the total synthesis of natural products.
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