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化驗
97%
折射率
n20/D 1.42 (lit.)
bp
140 °C (lit.)
密度
0.814 g/mL at 25 °C (lit.)
SMILES 字串
C=CCCC#N
InChI
1S/C5H7N/c1-2-3-4-5-6/h2H,1,3-4H2
InChI 密鑰
CFEYBLWMNFZOPB-UHFFFAOYSA-N
一般說明
4-Pentenenitrile (4-PN) is a terminal alkene nitrile. It is obtained from 3-pentenenitrile via cationic nickel hydride or cobalt catalyzed isomerization. 4-Pentenenitrile undergoes hydrocyanation in the presence of bidentate nickel complexes (catalysts) to yield 3-pentenenitrile. 4-PN undergoes gas-phase reaction with OH radicals and Cl atoms in the presence of synthetic air and various reference compounds.
應用
4-Pentenenitrile may be used to synthesize 4-pentenylamine.
訊號詞
Warning
危險分類
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral
儲存類別代碼
3 - Flammable liquids
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
個人防護裝備
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
其他客户在看
B Ozierenski et al.
Die Nahrung, 37(1), 5-14 (1993-01-01)
The effects of 5-vinyloxazolidine-2-thione (VOT), 1-cyano-3-butene (CYB) and various isothiocyanates on parameters of hepatic phase I and phase II biotransformation were investigated in male rats after oral treatment for 3 consecutive days. The compounds with the exception of CYB caused
Ligand Descriptor Analysis in Nickel-Catalysed Hydrocyanation: A Combined Experimental and Theoretical Study.
Burello E, et al.
Advanced Synthesis & Catalysis, 347(6), 803-810 (2005)
Gas-phase reactivity study of (E)-3-pentenenitrile and 4-pentenenitrile towards OH radicals and Cl atoms at atmospheric pressure.
Colomer JP, et al.
Atmospheric Environment, 61, 597-604 (2012)
New methods for alkaloid synthesis: Generation of indole-2, 3-diquinomethanes as a route to indole alkaloids.
Gallagher T and Magnus P.
Tetrahedron, 37(23), 3889-3897 (1981)
P Kloss et al.
Poultry science, 73(10), 1542-1551 (1994-10-01)
Glucosinolates and their breakdown products (nitriles) have long been implicated as toxic factors when feeding rapeseed (Brassica napus) meals and crambe (Crambe abyssinica) meals to poultry. Accordingly, various methods have been developed to remove these compounds from the meals to
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